fac-(2-Amido­ethyl-κ(2) C (1),O)trichlorido(urea-κO)tin(IV)

The Sn atom in the title compound, [Sn(C(3)H(6)NO)Cl(3)(CH(4)N(2)O)], is octa­hedrally coordinated within a CCl(3)NO donor set provided by a chelating amido­ethyl ligand (C and O), a urea-O atom and three facially arranged Cl atoms. Systematic variations in the Sn—Cl bond distances are correlated wi...

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Detalles Bibliográficos
Autores principales: Howie, R. Alan, de Lima, Geraldo M., Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201406/
https://www.ncbi.nlm.nih.gov/pubmed/22064619
http://dx.doi.org/10.1107/S1600536811038281
Descripción
Sumario:The Sn atom in the title compound, [Sn(C(3)H(6)NO)Cl(3)(CH(4)N(2)O)], is octa­hedrally coordinated within a CCl(3)NO donor set provided by a chelating amido­ethyl ligand (C and O), a urea-O atom and three facially arranged Cl atoms. Systematic variations in the Sn—Cl bond distances are correlated with the relative trans influence exerted by the C and carbonyl-O atoms. The three-dimensional crystal packing is stabilized by N—H⋯O and N—H⋯Cl hydrogen bonds.

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