Cargando…
fac-(2-Amidoethyl-κ(2) C (1),O)trichlorido(urea-κO)tin(IV)
The Sn atom in the title compound, [Sn(C(3)H(6)NO)Cl(3)(CH(4)N(2)O)], is octahedrally coordinated within a CCl(3)NO donor set provided by a chelating amidoethyl ligand (C and O), a urea-O atom and three facially arranged Cl atoms. Systematic variations in the Sn—Cl bond distances are correlated wi...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201406/ https://www.ncbi.nlm.nih.gov/pubmed/22064619 http://dx.doi.org/10.1107/S1600536811038281 |
| _version_ | 1782214867295404032 |
|---|---|
| author | Howie, R. Alan de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
| author_facet | Howie, R. Alan de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
| author_sort | Howie, R. Alan |
| collection | PubMed |
| description | The Sn atom in the title compound, [Sn(C(3)H(6)NO)Cl(3)(CH(4)N(2)O)], is octahedrally coordinated within a CCl(3)NO donor set provided by a chelating amidoethyl ligand (C and O), a urea-O atom and three facially arranged Cl atoms. Systematic variations in the Sn—Cl bond distances are correlated with the relative trans influence exerted by the C and carbonyl-O atoms. The three-dimensional crystal packing is stabilized by N—H⋯O and N—H⋯Cl hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3201406 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32014062011-11-06 fac-(2-Amidoethyl-κ(2) C (1),O)trichlorido(urea-κO)tin(IV) Howie, R. Alan de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(3)H(6)NO)Cl(3)(CH(4)N(2)O)], is octahedrally coordinated within a CCl(3)NO donor set provided by a chelating amidoethyl ligand (C and O), a urea-O atom and three facially arranged Cl atoms. Systematic variations in the Sn—Cl bond distances are correlated with the relative trans influence exerted by the C and carbonyl-O atoms. The three-dimensional crystal packing is stabilized by N—H⋯O and N—H⋯Cl hydrogen bonds. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201406/ /pubmed/22064619 http://dx.doi.org/10.1107/S1600536811038281 Text en © Howie et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Howie, R. Alan de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. fac-(2-Amidoethyl-κ(2) C (1),O)trichlorido(urea-κO)tin(IV) |
| title |
fac-(2-Amidoethyl-κ(2)
C
(1),O)trichlorido(urea-κO)tin(IV) |
| title_full |
fac-(2-Amidoethyl-κ(2)
C
(1),O)trichlorido(urea-κO)tin(IV) |
| title_fullStr |
fac-(2-Amidoethyl-κ(2)
C
(1),O)trichlorido(urea-κO)tin(IV) |
| title_full_unstemmed |
fac-(2-Amidoethyl-κ(2)
C
(1),O)trichlorido(urea-κO)tin(IV) |
| title_short |
fac-(2-Amidoethyl-κ(2)
C
(1),O)trichlorido(urea-κO)tin(IV) |
| title_sort | fac-(2-amidoethyl-κ(2)
c
(1),o)trichlorido(urea-κo)tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201406/ https://www.ncbi.nlm.nih.gov/pubmed/22064619 http://dx.doi.org/10.1107/S1600536811038281 |
| work_keys_str_mv | AT howieralan fac2amidoethylk2c1otrichloridoureakotiniv AT delimageraldom fac2amidoethylk2c1otrichloridoureakotiniv AT tiekinkedwardrt fac2amidoethylk2c1otrichloridoureakotiniv AT wardelljamesl fac2amidoethylk2c1otrichloridoureakotiniv AT wardellsolangemsv fac2amidoethylk2c1otrichloridoureakotiniv |