(E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide

The mol­ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), exists in a trans conformation with respect to the C=N double bond and is twisted, the dihedral angle between the two benzene rings being 24.17 (6)°. The meth­oxy group is almost co-planar with respect to the attached benzene...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Horkaew, Jirapa, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201407/
https://www.ncbi.nlm.nih.gov/pubmed/22064732
http://dx.doi.org/10.1107/S1600536811036579
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author Fun, Hoong-Kun
Horkaew, Jirapa
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Horkaew, Jirapa
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), exists in a trans conformation with respect to the C=N double bond and is twisted, the dihedral angle between the two benzene rings being 24.17 (6)°. The meth­oxy group is almost co-planar with respect to the attached benzene ring [C(m)—O—C—C (m = meth­yl) = −1.45 (17)°]. In the crystal, the mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into sheets parallel to the bc plane. These sheets are further connected into a three-dimensional network by weak C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-32014072011-11-06 (E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide Fun, Hoong-Kun Horkaew, Jirapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), exists in a trans conformation with respect to the C=N double bond and is twisted, the dihedral angle between the two benzene rings being 24.17 (6)°. The meth­oxy group is almost co-planar with respect to the attached benzene ring [C(m)—O—C—C (m = meth­yl) = −1.45 (17)°]. In the crystal, the mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into sheets parallel to the bc plane. These sheets are further connected into a three-dimensional network by weak C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201407/ /pubmed/22064732 http://dx.doi.org/10.1107/S1600536811036579 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Horkaew, Jirapa
Chantrapromma, Suchada
(E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide
title (E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide
title_full (E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide
title_fullStr (E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide
title_full_unstemmed (E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide
title_short (E)-4-Hy­droxy-N′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide
title_sort (e)-4-hy­droxy-n′-(3-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201407/
https://www.ncbi.nlm.nih.gov/pubmed/22064732
http://dx.doi.org/10.1107/S1600536811036579
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