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2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide
In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N—H bond in the C—SO(2)—NH—C segment orients itself away from the two ortho-methyl groups in the aniline benzene ring and towards the ortho-chloro group of the sulfonyl benzene ring. The molecule is bent at the S atom with a C—SO(2)—N...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201408/ https://www.ncbi.nlm.nih.gov/pubmed/22064772 http://dx.doi.org/10.1107/S1600536811037767 |
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author | Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme |
author_facet | Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme |
author_sort | Rodrigues, Vinola Z. |
collection | PubMed |
description | In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N—H bond in the C—SO(2)—NH—C segment orients itself away from the two ortho-methyl groups in the aniline benzene ring and towards the ortho-chloro group of the sulfonyl benzene ring. The molecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −100.48 (18)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 69.6 (1)°. Intermolecular N—H⋯O hydrogen bonds link the molecules into infinite chains. |
format | Online Article Text |
id | pubmed-3201408 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014082011-11-06 2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N—H bond in the C—SO(2)—NH—C segment orients itself away from the two ortho-methyl groups in the aniline benzene ring and towards the ortho-chloro group of the sulfonyl benzene ring. The molecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −100.48 (18)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 69.6 (1)°. Intermolecular N—H⋯O hydrogen bonds link the molecules into infinite chains. International Union of Crystallography 2011-09-20 /pmc/articles/PMC3201408/ /pubmed/22064772 http://dx.doi.org/10.1107/S1600536811037767 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme 2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide |
title | 2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide |
title_full | 2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide |
title_fullStr | 2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide |
title_full_unstemmed | 2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide |
title_short | 2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide |
title_sort | 2,4-dichloro-n-(2,6-dimethylphenyl)benzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201408/ https://www.ncbi.nlm.nih.gov/pubmed/22064772 http://dx.doi.org/10.1107/S1600536811037767 |
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