N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide

In the title compound, C(16)H(17)Cl(3)N(3)O(2)P, the P—N bonds in the P(O)[NH(2—CH(3))C(6)H(4)](2) unit [1.623 (4) and 1.637 (3) Å] are shorter than the P—N bond in the C(O)NHP(O) fragment [1.704 (3) Å]. The phosphoryl and carbonyl groups are anti with respect to each other and the P atom has a dist...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Keikha, Mojtaba, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201409/
https://www.ncbi.nlm.nih.gov/pubmed/22064803
http://dx.doi.org/10.1107/S1600536811039511
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author Pourayoubi, Mehrdad
Keikha, Mojtaba
Parvez, Masood
author_facet Pourayoubi, Mehrdad
Keikha, Mojtaba
Parvez, Masood
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title compound, C(16)H(17)Cl(3)N(3)O(2)P, the P—N bonds in the P(O)[NH(2—CH(3))C(6)H(4)](2) unit [1.623 (4) and 1.637 (3) Å] are shorter than the P—N bond in the C(O)NHP(O) fragment [1.704 (3) Å]. The phosphoryl and carbonyl groups are anti with respect to each other and the P atom has a distorted tetra­hedral configuration. In the crystal, adjacent mol­ecules are linked via N—H⋯O(P) and N—H⋯O(C) hydrogen bonds into an extended chain parallel to [101].
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spelling pubmed-32014092011-11-06 N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide Pourayoubi, Mehrdad Keikha, Mojtaba Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)Cl(3)N(3)O(2)P, the P—N bonds in the P(O)[NH(2—CH(3))C(6)H(4)](2) unit [1.623 (4) and 1.637 (3) Å] are shorter than the P—N bond in the C(O)NHP(O) fragment [1.704 (3) Å]. The phosphoryl and carbonyl groups are anti with respect to each other and the P atom has a distorted tetra­hedral configuration. In the crystal, adjacent mol­ecules are linked via N—H⋯O(P) and N—H⋯O(C) hydrogen bonds into an extended chain parallel to [101]. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201409/ /pubmed/22064803 http://dx.doi.org/10.1107/S1600536811039511 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Keikha, Mojtaba
Parvez, Masood
N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_full N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_fullStr N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_full_unstemmed N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_short N,N′-Bis(2-methyl­phen­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_sort n,n′-bis(2-methyl­phen­yl)-n′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201409/
https://www.ncbi.nlm.nih.gov/pubmed/22064803
http://dx.doi.org/10.1107/S1600536811039511
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AT parvezmasood nnbis2methylphenyln222trichloroacetylphosphorictriamide

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