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Poly[[(2,2′-bipyridine)(μ (3)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium] monohydrate]
The title compound, {[Cd(C(8)H(8)O(5))(C(10)H(8)N(2))]·H(2)O}(n), was obtained by the reaction of cadmium acetate with 2,2′-bipyridine and 7-oxabicyclo(2.2.1)heptane-2,3-dicarboxylic anhydride. The Cd(II) atom is seven-coordinated in a distorted pentagonal–bipyramidal configuration, defined by...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201414/ https://www.ncbi.nlm.nih.gov/pubmed/22065044 http://dx.doi.org/10.1107/S1600536811036634 |
Sumario: | The title compound, {[Cd(C(8)H(8)O(5))(C(10)H(8)N(2))]·H(2)O}(n), was obtained by the reaction of cadmium acetate with 2,2′-bipyridine and 7-oxabicyclo(2.2.1)heptane-2,3-dicarboxylic anhydride. The Cd(II) atom is seven-coordinated in a distorted pentagonal–bipyramidal configuration, defined by five O atoms from the carboxylate groups of three 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato ligands and two N atoms from the 2,2′-bipyridine ligand. Two O atoms link two Cd(II) atoms, forming a dinuclear center: the Cd—O—Cd bridging angle is 110.19 (6)°. The polymeric structure extends along [100] and is linked by intermolecular O—H⋯O hydrogen bonds involving the solvent water molecule. Extensive π–π stacking exists between 2,2-bypiridine ligands along [010] with centroid-centroid distance of 3.650 (2) Å |
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