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4-Chloro-N-(2,3-dimethylphenyl)-2-methylbenzenesulfonamide
The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains two independent moleules. The conformation of the N—H bonds are anti to the ortho-methyl groups in the sulfonyl benzene rings of both the molecules, while the N—H bonds are anti to the ortho- and meta-methyl groups in the anili...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201417/ https://www.ncbi.nlm.nih.gov/pubmed/22065412 http://dx.doi.org/10.1107/S1600536811037536 |
| Sumario: | The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains two independent moleules. The conformation of the N—H bonds are anti to the ortho-methyl groups in the sulfonyl benzene rings of both the molecules, while the N—H bonds are anti to the ortho- and meta-methyl groups in the aniline ring of one of the molecules and syn in the other. Furthermore, the torsion angles of the C—SO(2)—NH—C segments in the two molecules of are −66.8 (3) and 70.3 (3)°. The sulfonyl and the aniline benzene rings are oriented at angles of 44.1 (1) and 39.7 (1)° in the two molecules. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into dimers. |
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