4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide

The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains two independent moleules. The conformation of the N—H bonds are anti to the ortho-methyl groups in the sulfonyl benzene rings of both the mol­ecules, while the N—H bonds are anti to the ortho- and meta-methyl groups in the anili...

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Autores principales: Rodrigues, Vinola Z., Foro, Sabine, Gowda, B. Thimme, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201417/
https://www.ncbi.nlm.nih.gov/pubmed/22065412
http://dx.doi.org/10.1107/S1600536811037536
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author Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
Shakuntala, K.
author_facet Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
Shakuntala, K.
author_sort Rodrigues, Vinola Z.
collection PubMed
description The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains two independent moleules. The conformation of the N—H bonds are anti to the ortho-methyl groups in the sulfonyl benzene rings of both the mol­ecules, while the N—H bonds are anti to the ortho- and meta-methyl groups in the aniline ring of one of the mol­ecules and syn in the other. Furthermore, the torsion angles of the C—SO(2)—NH—C segments in the two mol­ecules of are −66.8 (3) and 70.3 (3)°. The sulfonyl and the aniline benzene rings are oriented at angles of 44.1 (1) and 39.7 (1)° in the two mol­ecules. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into dimers.
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spelling pubmed-32014172011-11-06 4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Shakuntala, K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains two independent moleules. The conformation of the N—H bonds are anti to the ortho-methyl groups in the sulfonyl benzene rings of both the mol­ecules, while the N—H bonds are anti to the ortho- and meta-methyl groups in the aniline ring of one of the mol­ecules and syn in the other. Furthermore, the torsion angles of the C—SO(2)—NH—C segments in the two mol­ecules of are −66.8 (3) and 70.3 (3)°. The sulfonyl and the aniline benzene rings are oriented at angles of 44.1 (1) and 39.7 (1)° in the two mol­ecules. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into dimers. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201417/ /pubmed/22065412 http://dx.doi.org/10.1107/S1600536811037536 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
Shakuntala, K.
4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide
title 4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide
title_full 4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide
title_fullStr 4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide
title_full_unstemmed 4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide
title_short 4-Chloro-N-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide
title_sort 4-chloro-n-(2,3-dimethyl­phen­yl)-2-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201417/
https://www.ncbi.nlm.nih.gov/pubmed/22065412
http://dx.doi.org/10.1107/S1600536811037536
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AT forosabine 4chloron23dimethylphenyl2methylbenzenesulfonamide
AT gowdabthimme 4chloron23dimethylphenyl2methylbenzenesulfonamide
AT shakuntalak 4chloron23dimethylphenyl2methylbenzenesulfonamide

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