1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene

In the title compound, C(40)H(32)Cl(2)O(4), the two chloro­benzene rings are in syn orientations with respect to the naphthalene ring system and make dihedral angles of 57.12 (6) and 85.74 (6)° with it. The benzene rings of the benz­yloxy group make dihedral angles of 75.34 (6) and 83.95 (7)°, with...

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Detalles Bibliográficos
Autores principales: Takada, Teruhisa, Hijikata, Daichi, Okamoto, Akiko, Oike, Hideaki, Yonezawa, Noriyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201419/
https://www.ncbi.nlm.nih.gov/pubmed/22065558
http://dx.doi.org/10.1107/S1600536811035495
Descripción
Sumario:In the title compound, C(40)H(32)Cl(2)O(4), the two chloro­benzene rings are in syn orientations with respect to the naphthalene ring system and make dihedral angles of 57.12 (6) and 85.74 (6)° with it. The benzene rings of the benz­yloxy group make dihedral angles of 75.34 (6) and 83.95 (7)°, with the naphthalene ring system. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯Cl inter­actions between the methyl­ene H atoms of the benz­yloxy group and the Cl atoms in adjacent mol­ecules. Furthermore, centrosymmetrically related mol­ecules are linked into dimeric units by pairs of C—H⋯π inter­actions.

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