1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene

In the title compound, C(40)H(32)Cl(2)O(4), the two chloro­benzene rings are in syn orientations with respect to the naphthalene ring system and make dihedral angles of 57.12 (6) and 85.74 (6)° with it. The benzene rings of the benz­yloxy group make dihedral angles of 75.34 (6) and 83.95 (7)°, with...

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Autores principales: Takada, Teruhisa, Hijikata, Daichi, Okamoto, Akiko, Oike, Hideaki, Yonezawa, Noriyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201419/
https://www.ncbi.nlm.nih.gov/pubmed/22065558
http://dx.doi.org/10.1107/S1600536811035495
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author Takada, Teruhisa
Hijikata, Daichi
Okamoto, Akiko
Oike, Hideaki
Yonezawa, Noriyuki
author_facet Takada, Teruhisa
Hijikata, Daichi
Okamoto, Akiko
Oike, Hideaki
Yonezawa, Noriyuki
author_sort Takada, Teruhisa
collection PubMed
description In the title compound, C(40)H(32)Cl(2)O(4), the two chloro­benzene rings are in syn orientations with respect to the naphthalene ring system and make dihedral angles of 57.12 (6) and 85.74 (6)° with it. The benzene rings of the benz­yloxy group make dihedral angles of 75.34 (6) and 83.95 (7)°, with the naphthalene ring system. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯Cl inter­actions between the methyl­ene H atoms of the benz­yloxy group and the Cl atoms in adjacent mol­ecules. Furthermore, centrosymmetrically related mol­ecules are linked into dimeric units by pairs of C—H⋯π inter­actions.
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spelling pubmed-32014192011-11-06 1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene Takada, Teruhisa Hijikata, Daichi Okamoto, Akiko Oike, Hideaki Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(40)H(32)Cl(2)O(4), the two chloro­benzene rings are in syn orientations with respect to the naphthalene ring system and make dihedral angles of 57.12 (6) and 85.74 (6)° with it. The benzene rings of the benz­yloxy group make dihedral angles of 75.34 (6) and 83.95 (7)°, with the naphthalene ring system. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯Cl inter­actions between the methyl­ene H atoms of the benz­yloxy group and the Cl atoms in adjacent mol­ecules. Furthermore, centrosymmetrically related mol­ecules are linked into dimeric units by pairs of C—H⋯π inter­actions. International Union of Crystallography 2011-09-03 /pmc/articles/PMC3201419/ /pubmed/22065558 http://dx.doi.org/10.1107/S1600536811035495 Text en © Takada et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Takada, Teruhisa
Hijikata, Daichi
Okamoto, Akiko
Oike, Hideaki
Yonezawa, Noriyuki
1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene
title 1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene
title_full 1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene
title_fullStr 1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene
title_full_unstemmed 1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene
title_short 1,2-Bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene
title_sort 1,2-bis(benz­yloxy)-1,2-bis­(4-chloro­phen­yl)-3,8-dimeth­oxy­acenaphthene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201419/
https://www.ncbi.nlm.nih.gov/pubmed/22065558
http://dx.doi.org/10.1107/S1600536811035495
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AT okamotoakiko 12bisbenzyloxy12bis4chlorophenyl38dimethoxyacenaphthene
AT oikehideaki 12bisbenzyloxy12bis4chlorophenyl38dimethoxyacenaphthene
AT yonezawanoriyuki 12bisbenzyloxy12bis4chlorophenyl38dimethoxyacenaphthene

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