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[Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)

The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta­coordinate tungsten(II) complex with a capped–octa­hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 1...

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Detalles Bibliográficos
Autores principales: Strasser, Christoph E., Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201421/
https://www.ncbi.nlm.nih.gov/pubmed/22065685
http://dx.doi.org/10.1107/S1600536811038104
Descripción
Sumario:The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta­coordinate tungsten(II) complex with a capped–octa­hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis­(4-methyl-1,3-thia­zol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, mol­ecules are linked into chains parallel to [201] by weak C—H⋯O contacts between the CH(2) group of the bis­(4-methyl­thia­zol-2-yl)methane ligand and the O atom of the capping CO group.