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[Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)

The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta­coordinate tungsten(II) complex with a capped–octa­hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 1...

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Autores principales: Strasser, Christoph E., Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201421/
https://www.ncbi.nlm.nih.gov/pubmed/22065685
http://dx.doi.org/10.1107/S1600536811038104
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author Strasser, Christoph E.
Cronje, Stephanie
Raubenheimer, Helgard G.
author_facet Strasser, Christoph E.
Cronje, Stephanie
Raubenheimer, Helgard G.
author_sort Strasser, Christoph E.
collection PubMed
description The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta­coordinate tungsten(II) complex with a capped–octa­hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis­(4-methyl-1,3-thia­zol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, mol­ecules are linked into chains parallel to [201] by weak C—H⋯O contacts between the CH(2) group of the bis­(4-methyl­thia­zol-2-yl)methane ligand and the O atom of the capping CO group.
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spelling pubmed-32014212011-11-06 [Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II) Strasser, Christoph E. Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta­coordinate tungsten(II) complex with a capped–octa­hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis­(4-methyl-1,3-thia­zol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, mol­ecules are linked into chains parallel to [201] by weak C—H⋯O contacts between the CH(2) group of the bis­(4-methyl­thia­zol-2-yl)methane ligand and the O atom of the capping CO group. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201421/ /pubmed/22065685 http://dx.doi.org/10.1107/S1600536811038104 Text en © Strasser et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Strasser, Christoph E.
Cronje, Stephanie
Raubenheimer, Helgard G.
[Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)
title [Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)
title_full [Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)
title_fullStr [Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)
title_full_unstemmed [Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)
title_short [Bis­(4-methyl-1,3-thia­zol-2-yl-κN)methane]­tricarbonyl­dichlorido­tungsten(II)
title_sort [bis­(4-methyl-1,3-thia­zol-2-yl-κn)methane]­tricarbonyl­dichlorido­tungsten(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201421/
https://www.ncbi.nlm.nih.gov/pubmed/22065685
http://dx.doi.org/10.1107/S1600536811038104
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