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[Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II)
The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a heptacoordinate tungsten(II) complex with a capped–octahedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 1...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201421/ https://www.ncbi.nlm.nih.gov/pubmed/22065685 http://dx.doi.org/10.1107/S1600536811038104 |
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author | Strasser, Christoph E. Cronje, Stephanie Raubenheimer, Helgard G. |
author_facet | Strasser, Christoph E. Cronje, Stephanie Raubenheimer, Helgard G. |
author_sort | Strasser, Christoph E. |
collection | PubMed |
description | The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a heptacoordinate tungsten(II) complex with a capped–octahedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis(4-methyl-1,3-thiazol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, molecules are linked into chains parallel to [201] by weak C—H⋯O contacts between the CH(2) group of the bis(4-methylthiazol-2-yl)methane ligand and the O atom of the capping CO group. |
format | Online Article Text |
id | pubmed-3201421 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014212011-11-06 [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) Strasser, Christoph E. Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a heptacoordinate tungsten(II) complex with a capped–octahedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis(4-methyl-1,3-thiazol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, molecules are linked into chains parallel to [201] by weak C—H⋯O contacts between the CH(2) group of the bis(4-methylthiazol-2-yl)methane ligand and the O atom of the capping CO group. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201421/ /pubmed/22065685 http://dx.doi.org/10.1107/S1600536811038104 Text en © Strasser et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Strasser, Christoph E. Cronje, Stephanie Raubenheimer, Helgard G. [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
title | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
title_full | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
title_fullStr | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
title_full_unstemmed | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
title_short | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
title_sort | [bis(4-methyl-1,3-thiazol-2-yl-κn)methane]tricarbonyldichloridotungsten(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201421/ https://www.ncbi.nlm.nih.gov/pubmed/22065685 http://dx.doi.org/10.1107/S1600536811038104 |
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