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Deacetylnomilin monohydrate
In the title compound (systematic name 1-hydroxy-1,2-dihydroobacunoic acid 3,4-lactone monohydrate), C(26)H(32)O(8)·H(2)O, the dihedral angles between the planes of the ester groups and the furan plane are 43.06 (12) and 56.06 (7)°, while that between the furan plane and the keto group is 58.50 (9...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201424/ https://www.ncbi.nlm.nih.gov/pubmed/22065825 http://dx.doi.org/10.1107/S1600536811035033 |
| _version_ | 1782214871358636032 |
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| author | Li, Guo-Qiang Ye, Yong-Shu Yang, Yi-Ting Luo, Hu-Jie Li, Yao-Lan |
| author_facet | Li, Guo-Qiang Ye, Yong-Shu Yang, Yi-Ting Luo, Hu-Jie Li, Yao-Lan |
| author_sort | Li, Guo-Qiang |
| collection | PubMed |
| description | In the title compound (systematic name 1-hydroxy-1,2-dihydroobacunoic acid 3,4-lactone monohydrate), C(26)H(32)O(8)·H(2)O, the dihedral angles between the planes of the ester groups and the furan plane are 43.06 (12) and 56.06 (7)°, while that between the furan plane and the keto group is 58.50 (9)°. The A/B, B/C and C/D ring junctions are all trans-fused. Intermolecular O—H⋯O hydrogen bonds between the hydroxy and carbonyl groups and the water molecule give rise to a three-dimensional structure. |
| format | Online Article Text |
| id | pubmed-3201424 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32014242011-11-06 Deacetylnomilin monohydrate Li, Guo-Qiang Ye, Yong-Shu Yang, Yi-Ting Luo, Hu-Jie Li, Yao-Lan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound (systematic name 1-hydroxy-1,2-dihydroobacunoic acid 3,4-lactone monohydrate), C(26)H(32)O(8)·H(2)O, the dihedral angles between the planes of the ester groups and the furan plane are 43.06 (12) and 56.06 (7)°, while that between the furan plane and the keto group is 58.50 (9)°. The A/B, B/C and C/D ring junctions are all trans-fused. Intermolecular O—H⋯O hydrogen bonds between the hydroxy and carbonyl groups and the water molecule give rise to a three-dimensional structure. International Union of Crystallography 2011-09-03 /pmc/articles/PMC3201424/ /pubmed/22065825 http://dx.doi.org/10.1107/S1600536811035033 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Li, Guo-Qiang Ye, Yong-Shu Yang, Yi-Ting Luo, Hu-Jie Li, Yao-Lan Deacetylnomilin monohydrate |
| title | Deacetylnomilin monohydrate |
| title_full | Deacetylnomilin monohydrate |
| title_fullStr | Deacetylnomilin monohydrate |
| title_full_unstemmed | Deacetylnomilin monohydrate |
| title_short | Deacetylnomilin monohydrate |
| title_sort | deacetylnomilin monohydrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201424/ https://www.ncbi.nlm.nih.gov/pubmed/22065825 http://dx.doi.org/10.1107/S1600536811035033 |
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