Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4)

The title compound, Mg(7)(PO(4))(2)(HPO(4))(4), was synthesized by the hydro­thermal method. The structure is based on a framework of edge- and corner-sharing MgO(6) and MgO(4)(OH)(2) octa­hedra, an MgO(5) polyhedron, PO(4) and PO(3)(OH) tetra­hedra. All atoms are in general positions except for one...

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Autores principales: Assani, Abderrazzak, Saadi, Mohamed, Zriouil, Mohammed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201425/
https://www.ncbi.nlm.nih.gov/pubmed/22064383
http://dx.doi.org/10.1107/S1600536811036361
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author Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
author_facet Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
author_sort Assani, Abderrazzak
collection PubMed
description The title compound, Mg(7)(PO(4))(2)(HPO(4))(4), was synthesized by the hydro­thermal method. The structure is based on a framework of edge- and corner-sharing MgO(6) and MgO(4)(OH)(2) octa­hedra, an MgO(5) polyhedron, PO(4) and PO(3)(OH) tetra­hedra. All atoms are in general positions except for one Mg atom, which is located on a crystallographic inversion centre. The OH groups, bridging Mg–(OH)–P, are involved in strong hydrogen bonds. Compounds with the general formula M (7)(PO(4))(2)(HPO(4))(4) (M = Mg, Mn, Fe and Co) are all isostructural with their homologue arsenate Mg(7)(AsO(4))(2)(HAsO(4))(4).
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spelling pubmed-32014252011-11-06 Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4) Assani, Abderrazzak Saadi, Mohamed Zriouil, Mohammed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Mg(7)(PO(4))(2)(HPO(4))(4), was synthesized by the hydro­thermal method. The structure is based on a framework of edge- and corner-sharing MgO(6) and MgO(4)(OH)(2) octa­hedra, an MgO(5) polyhedron, PO(4) and PO(3)(OH) tetra­hedra. All atoms are in general positions except for one Mg atom, which is located on a crystallographic inversion centre. The OH groups, bridging Mg–(OH)–P, are involved in strong hydrogen bonds. Compounds with the general formula M (7)(PO(4))(2)(HPO(4))(4) (M = Mg, Mn, Fe and Co) are all isostructural with their homologue arsenate Mg(7)(AsO(4))(2)(HAsO(4))(4). International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201425/ /pubmed/22064383 http://dx.doi.org/10.1107/S1600536811036361 Text en © Assani et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Assani, Abderrazzak
Saadi, Mohamed
Zriouil, Mohammed
El Ammari, Lahcen
Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4)
title Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4)
title_full Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4)
title_fullStr Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4)
title_full_unstemmed Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4)
title_short Heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: Mg(7)(PO(4))(2)(HPO(4))(4)
title_sort heptamagnesium bis­(phosphate) tetra­kis­(hydrogen phosphate) with strong hydrogen bonds: mg(7)(po(4))(2)(hpo(4))(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201425/
https://www.ncbi.nlm.nih.gov/pubmed/22064383
http://dx.doi.org/10.1107/S1600536811036361
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