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Tetrakis(μ(2)-2-phenoxypropionato)-κ(3) O,O′:O′;κ(3) O:O,O′;κ(4) O:O′-bis[(1,10-phenanthroline-κ(2) N,N′)(2-phenoxypropionato-κ(2) O,O′)cerium(III)]
In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phenoxypropionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline molecule, two O atoms from a chelati...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201429/ https://www.ncbi.nlm.nih.gov/pubmed/22064783 http://dx.doi.org/10.1107/S1600536811036129 |
| Sumario: | In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phenoxypropionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline molecule, two O atoms from a chelating carboxylate, two O atoms derived from a μ(3)-carboxylate and two O atoms derived from two μ(2)-carboxylate ligands in a distorted CeN(2)O(7) monocapped square-antiprismatic geometry. |
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