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Tetrakis(μ(2)-2-phenoxypropionato)-κ(3) O,O′:O′;κ(3) O:O,O′;κ(4) O:O′-bis[(1,10-phenanthroline-κ(2) N,N′)(2-phenoxypropionato-κ(2) O,O′)cerium(III)]
In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phenoxypropionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline molecule, two O atoms from a chelati...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201429/ https://www.ncbi.nlm.nih.gov/pubmed/22064783 http://dx.doi.org/10.1107/S1600536811036129 |
| _version_ | 1782214872454397952 |
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| author | Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang |
| author_facet | Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang |
| author_sort | Shen, Jin-Bei |
| collection | PubMed |
| description | In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phenoxypropionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline molecule, two O atoms from a chelating carboxylate, two O atoms derived from a μ(3)-carboxylate and two O atoms derived from two μ(2)-carboxylate ligands in a distorted CeN(2)O(7) monocapped square-antiprismatic geometry. |
| format | Online Article Text |
| id | pubmed-3201429 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32014292011-11-06 Tetrakis(μ(2)-2-phenoxypropionato)-κ(3) O,O′:O′;κ(3) O:O,O′;κ(4) O:O′-bis[(1,10-phenanthroline-κ(2) N,N′)(2-phenoxypropionato-κ(2) O,O′)cerium(III)] Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phenoxypropionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline molecule, two O atoms from a chelating carboxylate, two O atoms derived from a μ(3)-carboxylate and two O atoms derived from two μ(2)-carboxylate ligands in a distorted CeN(2)O(7) monocapped square-antiprismatic geometry. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201429/ /pubmed/22064783 http://dx.doi.org/10.1107/S1600536811036129 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Tetrakis(μ(2)-2-phenoxypropionato)-κ(3) O,O′:O′;κ(3) O:O,O′;κ(4) O:O′-bis[(1,10-phenanthroline-κ(2) N,N′)(2-phenoxypropionato-κ(2) O,O′)cerium(III)] |
| title | Tetrakis(μ(2)-2-phenoxypropionato)-κ(3)
O,O′:O′;κ(3)
O:O,O′;κ(4)
O:O′-bis[(1,10-phenanthroline-κ(2)
N,N′)(2-phenoxypropionato-κ(2)
O,O′)cerium(III)] |
| title_full | Tetrakis(μ(2)-2-phenoxypropionato)-κ(3)
O,O′:O′;κ(3)
O:O,O′;κ(4)
O:O′-bis[(1,10-phenanthroline-κ(2)
N,N′)(2-phenoxypropionato-κ(2)
O,O′)cerium(III)] |
| title_fullStr | Tetrakis(μ(2)-2-phenoxypropionato)-κ(3)
O,O′:O′;κ(3)
O:O,O′;κ(4)
O:O′-bis[(1,10-phenanthroline-κ(2)
N,N′)(2-phenoxypropionato-κ(2)
O,O′)cerium(III)] |
| title_full_unstemmed | Tetrakis(μ(2)-2-phenoxypropionato)-κ(3)
O,O′:O′;κ(3)
O:O,O′;κ(4)
O:O′-bis[(1,10-phenanthroline-κ(2)
N,N′)(2-phenoxypropionato-κ(2)
O,O′)cerium(III)] |
| title_short | Tetrakis(μ(2)-2-phenoxypropionato)-κ(3)
O,O′:O′;κ(3)
O:O,O′;κ(4)
O:O′-bis[(1,10-phenanthroline-κ(2)
N,N′)(2-phenoxypropionato-κ(2)
O,O′)cerium(III)] |
| title_sort | tetrakis(μ(2)-2-phenoxypropionato)-κ(3)
o,o′:o′;κ(3)
o:o,o′;κ(4)
o:o′-bis[(1,10-phenanthroline-κ(2)
n,n′)(2-phenoxypropionato-κ(2)
o,o′)cerium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201429/ https://www.ncbi.nlm.nih.gov/pubmed/22064783 http://dx.doi.org/10.1107/S1600536811036129 |
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