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Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate]
The title compound, {[La(4)(CH(3)CO(2))(10)(C(2)O(4))(H(2)O)(2)]·2H(2)O}(n), exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five ace...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201431/ https://www.ncbi.nlm.nih.gov/pubmed/22064832 http://dx.doi.org/10.1107/S1600536811038037 |
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author | Di, Wen-Jing Lan, Shao-Min Zhang, Qun Liang, Yun-Xiao |
author_facet | Di, Wen-Jing Lan, Shao-Min Zhang, Qun Liang, Yun-Xiao |
author_sort | Di, Wen-Jing |
collection | PubMed |
description | The title compound, {[La(4)(CH(3)CO(2))(10)(C(2)O(4))(H(2)O)(2)]·2H(2)O}(n), exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five acetate ligands, one coordinated water molecule and one uncoordinated water molecule. The coordination numbers of the two La ions are 9 and 10. Adjacent layers of the structure, which extend parallel to (100), are linked by O–H⋯O hydrogen bonds and are also held together by van der Waals interactions between the CH(3) groups of the acetate anions. |
format | Online Article Text |
id | pubmed-3201431 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014312011-11-06 Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate] Di, Wen-Jing Lan, Shao-Min Zhang, Qun Liang, Yun-Xiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[La(4)(CH(3)CO(2))(10)(C(2)O(4))(H(2)O)(2)]·2H(2)O}(n), exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five acetate ligands, one coordinated water molecule and one uncoordinated water molecule. The coordination numbers of the two La ions are 9 and 10. Adjacent layers of the structure, which extend parallel to (100), are linked by O–H⋯O hydrogen bonds and are also held together by van der Waals interactions between the CH(3) groups of the acetate anions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201431/ /pubmed/22064832 http://dx.doi.org/10.1107/S1600536811038037 Text en © Di et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Di, Wen-Jing Lan, Shao-Min Zhang, Qun Liang, Yun-Xiao Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate] |
title | Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate] |
title_full | Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate] |
title_fullStr | Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate] |
title_full_unstemmed | Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate] |
title_short | Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(III)] dihydrate] |
title_sort | poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetatodiaqua-μ(2)-oxalato-tetralanthanum(iii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201431/ https://www.ncbi.nlm.nih.gov/pubmed/22064832 http://dx.doi.org/10.1107/S1600536811038037 |
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