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Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate]

The title compound, {[La(4)(CH(3)CO(2))(10)(C(2)O(4))(H(2)O)(2)]·2H(2)O}(n), exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five ace...

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Detalles Bibliográficos
Autores principales: Di, Wen-Jing, Lan, Shao-Min, Zhang, Qun, Liang, Yun-Xiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201431/
https://www.ncbi.nlm.nih.gov/pubmed/22064832
http://dx.doi.org/10.1107/S1600536811038037
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author Di, Wen-Jing
Lan, Shao-Min
Zhang, Qun
Liang, Yun-Xiao
author_facet Di, Wen-Jing
Lan, Shao-Min
Zhang, Qun
Liang, Yun-Xiao
author_sort Di, Wen-Jing
collection PubMed
description The title compound, {[La(4)(CH(3)CO(2))(10)(C(2)O(4))(H(2)O)(2)]·2H(2)O}(n), exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five acetate ligands, one coordinated water mol­ecule and one uncoordinated water mol­ecule. The coordination numbers of the two La ions are 9 and 10. Adjacent layers of the structure, which extend parallel to (100), are linked by O–H⋯O hydrogen bonds and are also held together by van der Waals inter­actions between the CH(3) groups of the acetate anions.
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spelling pubmed-32014312011-11-06 Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate] Di, Wen-Jing Lan, Shao-Min Zhang, Qun Liang, Yun-Xiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[La(4)(CH(3)CO(2))(10)(C(2)O(4))(H(2)O)(2)]·2H(2)O}(n), exhibits a two-dimensional layered structure with the oxalate and acetate ligands acting as bridges. The asymmetric unit contains two crystallographically independent lanthanum(III) ions, half of an oxalate ligand, five acetate ligands, one coordinated water mol­ecule and one uncoordinated water mol­ecule. The coordination numbers of the two La ions are 9 and 10. Adjacent layers of the structure, which extend parallel to (100), are linked by O–H⋯O hydrogen bonds and are also held together by van der Waals inter­actions between the CH(3) groups of the acetate anions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201431/ /pubmed/22064832 http://dx.doi.org/10.1107/S1600536811038037 Text en © Di et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Di, Wen-Jing
Lan, Shao-Min
Zhang, Qun
Liang, Yun-Xiao
Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate]
title Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate]
title_full Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate]
title_fullStr Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate]
title_full_unstemmed Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate]
title_short Poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(III)] dihydrate]
title_sort poly[[tetra-μ(3)-acetato-hexa-μ(2)-acetato­diaqua-μ(2)-oxalato-tetra­lanthanum(iii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201431/
https://www.ncbi.nlm.nih.gov/pubmed/22064832
http://dx.doi.org/10.1107/S1600536811038037
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