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{μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2) P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P—Au—Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The molecule exhibits a twofold symmetry axis. Stacks of the compound are formed throug...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201433/ https://www.ncbi.nlm.nih.gov/pubmed/22064923 http://dx.doi.org/10.1107/S1600536811038499 |
| _version_ | 1782214873346736128 |
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| author | Kriel, Frederik H. Fernandes, Manuel A. Coates, Judy |
| author_facet | Kriel, Frederik H. Fernandes, Manuel A. Coates, Judy |
| author_sort | Kriel, Frederik H. |
| collection | PubMed |
| description | The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P—Au—Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The molecule exhibits a twofold symmetry axis. Stacks of the compound are formed through intermolecular C—H⋯Cl interactions, while the tetrahydrofuran (THF) solvate is further attached to the stacks through weak C—H⋯O hydrogen bonding from the THF O atom to two separate H atoms on the complex. |
| format | Online Article Text |
| id | pubmed-3201433 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32014332011-11-06 {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2) P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate Kriel, Frederik H. Fernandes, Manuel A. Coates, Judy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P—Au—Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The molecule exhibits a twofold symmetry axis. Stacks of the compound are formed through intermolecular C—H⋯Cl interactions, while the tetrahydrofuran (THF) solvate is further attached to the stacks through weak C—H⋯O hydrogen bonding from the THF O atom to two separate H atoms on the complex. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201433/ /pubmed/22064923 http://dx.doi.org/10.1107/S1600536811038499 Text en © Kriel et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kriel, Frederik H. Fernandes, Manuel A. Coates, Judy {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2) P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate |
| title | {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2)
P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate |
| title_full | {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2)
P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate |
| title_fullStr | {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2)
P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate |
| title_full_unstemmed | {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2)
P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate |
| title_short | {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2)
P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate |
| title_sort | {μ-1,2-bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ(2)
p:p′}bis[chloridogold(i)] tetrahydrofuran disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201433/ https://www.ncbi.nlm.nih.gov/pubmed/22064923 http://dx.doi.org/10.1107/S1600536811038499 |
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