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catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]

In the polymeric structure of the title compound {[Li(2)(C(6)H(2)N(2)O(4))(2)Li(H(2)O)(2)Li(H(2)O)]·H(2)O}(n), the coordination of two independent Li(I) ions is distorted trigonal–bipyramidal and that of the other two independent Li(I) ions is distorted tetra­hedral. The former two Li(I) ions are br...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201440/
https://www.ncbi.nlm.nih.gov/pubmed/22058718
http://dx.doi.org/10.1107/S1600536811038992
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description In the polymeric structure of the title compound {[Li(2)(C(6)H(2)N(2)O(4))(2)Li(H(2)O)(2)Li(H(2)O)]·H(2)O}(n), the coordination of two independent Li(I) ions is distorted trigonal–bipyramidal and that of the other two independent Li(I) ions is distorted tetra­hedral. The former two Li(I) ions are bridged by hetero-ring N atoms of two independent pyridazine-3,6-dicarboxyl­ate ligands, making a dimeric moiety. The carboxyl­ato-O atoms of both bidentate ligands bridge the dimers to adjacent independent aqua-coordinated Li(I) ions, forming mol­ecular ribbons. The latter are bridged by ligand carboxyl­ato and aqua O atoms, forming mol­ecular layers parallel to (100) which are held together by an extended system of O—H⋯O hydrogen bonds.
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spelling pubmed-32014402011-11-06 catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric structure of the title compound {[Li(2)(C(6)H(2)N(2)O(4))(2)Li(H(2)O)(2)Li(H(2)O)]·H(2)O}(n), the coordination of two independent Li(I) ions is distorted trigonal–bipyramidal and that of the other two independent Li(I) ions is distorted tetra­hedral. The former two Li(I) ions are bridged by hetero-ring N atoms of two independent pyridazine-3,6-dicarboxyl­ate ligands, making a dimeric moiety. The carboxyl­ato-O atoms of both bidentate ligands bridge the dimers to adjacent independent aqua-coordinated Li(I) ions, forming mol­ecular ribbons. The latter are bridged by ligand carboxyl­ato and aqua O atoms, forming mol­ecular layers parallel to (100) which are held together by an extended system of O—H⋯O hydrogen bonds. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201440/ /pubmed/22058718 http://dx.doi.org/10.1107/S1600536811038992 Text en © Starosta and Leciejewicz 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]
title catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]
title_full catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]
title_fullStr catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]
title_full_unstemmed catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]
title_short catena-Poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]
title_sort catena-poly[[μ(2)-aqua-diaqua­bis­(μ(4)-pyridazine-3,6-dicarboxyl­ato)tetra­lithium] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201440/
https://www.ncbi.nlm.nih.gov/pubmed/22058718
http://dx.doi.org/10.1107/S1600536811038992
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