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catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate]
In the polymeric structure of the title compound {[Li(2)(C(6)H(2)N(2)O(4))(2)Li(H(2)O)(2)Li(H(2)O)]·H(2)O}(n), the coordination of two independent Li(I) ions is distorted trigonal–bipyramidal and that of the other two independent Li(I) ions is distorted tetrahedral. The former two Li(I) ions are br...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201440/ https://www.ncbi.nlm.nih.gov/pubmed/22058718 http://dx.doi.org/10.1107/S1600536811038992 |
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author | Starosta, Wojciech Leciejewicz, Janusz |
author_facet | Starosta, Wojciech Leciejewicz, Janusz |
author_sort | Starosta, Wojciech |
collection | PubMed |
description | In the polymeric structure of the title compound {[Li(2)(C(6)H(2)N(2)O(4))(2)Li(H(2)O)(2)Li(H(2)O)]·H(2)O}(n), the coordination of two independent Li(I) ions is distorted trigonal–bipyramidal and that of the other two independent Li(I) ions is distorted tetrahedral. The former two Li(I) ions are bridged by hetero-ring N atoms of two independent pyridazine-3,6-dicarboxylate ligands, making a dimeric moiety. The carboxylato-O atoms of both bidentate ligands bridge the dimers to adjacent independent aqua-coordinated Li(I) ions, forming molecular ribbons. The latter are bridged by ligand carboxylato and aqua O atoms, forming molecular layers parallel to (100) which are held together by an extended system of O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3201440 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014402011-11-06 catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric structure of the title compound {[Li(2)(C(6)H(2)N(2)O(4))(2)Li(H(2)O)(2)Li(H(2)O)]·H(2)O}(n), the coordination of two independent Li(I) ions is distorted trigonal–bipyramidal and that of the other two independent Li(I) ions is distorted tetrahedral. The former two Li(I) ions are bridged by hetero-ring N atoms of two independent pyridazine-3,6-dicarboxylate ligands, making a dimeric moiety. The carboxylato-O atoms of both bidentate ligands bridge the dimers to adjacent independent aqua-coordinated Li(I) ions, forming molecular ribbons. The latter are bridged by ligand carboxylato and aqua O atoms, forming molecular layers parallel to (100) which are held together by an extended system of O—H⋯O hydrogen bonds. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201440/ /pubmed/22058718 http://dx.doi.org/10.1107/S1600536811038992 Text en © Starosta and Leciejewicz 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Starosta, Wojciech Leciejewicz, Janusz catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] |
title |
catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] |
title_full |
catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] |
title_fullStr |
catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] |
title_full_unstemmed |
catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] |
title_short |
catena-Poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] |
title_sort | catena-poly[[μ(2)-aqua-diaquabis(μ(4)-pyridazine-3,6-dicarboxylato)tetralithium] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201440/ https://www.ncbi.nlm.nih.gov/pubmed/22058718 http://dx.doi.org/10.1107/S1600536811038992 |
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