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N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide

There are three independent mol­ecules in the asymmetric unit of the title compound, C(19)H(16)N(2)O(3), in which the dihedral angles between the naphthalene ring system and the benzene ring are 7.52 (16), 18.15 (18), and 13.9 (2)°. All the mol­ecules exist in the trans configuration with respect to...

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Autor principal: Li, Xiao-Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201446/
https://www.ncbi.nlm.nih.gov/pubmed/22065731
http://dx.doi.org/10.1107/S1600536811038153
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author Li, Xiao-Yan
author_facet Li, Xiao-Yan
author_sort Li, Xiao-Yan
collection PubMed
description There are three independent mol­ecules in the asymmetric unit of the title compound, C(19)H(16)N(2)O(3), in which the dihedral angles between the naphthalene ring system and the benzene ring are 7.52 (16), 18.15 (18), and 13.9 (2)°. All the mol­ecules exist in the trans configuration with respect to the methyl­idene units. In each mol­ecule there is one O—H⋯N and one N—H⋯O intra­molecular hydrogen bond. In the crystal, two of the mol­ecules are linked via a bifurcated N—H⋯(O,O) hydrogen bond. All three mol­ecules are further linked via C—H⋯O inter­actions.
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spelling pubmed-32014462011-11-06 N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide Li, Xiao-Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers There are three independent mol­ecules in the asymmetric unit of the title compound, C(19)H(16)N(2)O(3), in which the dihedral angles between the naphthalene ring system and the benzene ring are 7.52 (16), 18.15 (18), and 13.9 (2)°. All the mol­ecules exist in the trans configuration with respect to the methyl­idene units. In each mol­ecule there is one O—H⋯N and one N—H⋯O intra­molecular hydrogen bond. In the crystal, two of the mol­ecules are linked via a bifurcated N—H⋯(O,O) hydrogen bond. All three mol­ecules are further linked via C—H⋯O inter­actions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201446/ /pubmed/22065731 http://dx.doi.org/10.1107/S1600536811038153 Text en © Xiao-Yan Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xiao-Yan
N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide
title N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide
title_full N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide
title_fullStr N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide
title_full_unstemmed N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide
title_short N′-[(1E)-(2-Hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide
title_sort n′-[(1e)-(2-hy­droxy­naphthalen-1-yl)methyl­idene]-2-meth­oxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201446/
https://www.ncbi.nlm.nih.gov/pubmed/22065731
http://dx.doi.org/10.1107/S1600536811038153
work_keys_str_mv AT lixiaoyan n1e2hydroxynaphthalen1ylmethylidene2methoxybenzohydrazide