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N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide
There are three independent molecules in the asymmetric unit of the title compound, C(19)H(16)N(2)O(3), in which the dihedral angles between the naphthalene ring system and the benzene ring are 7.52 (16), 18.15 (18), and 13.9 (2)°. All the molecules exist in the trans configuration with respect to...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201446/ https://www.ncbi.nlm.nih.gov/pubmed/22065731 http://dx.doi.org/10.1107/S1600536811038153 |
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author | Li, Xiao-Yan |
author_facet | Li, Xiao-Yan |
author_sort | Li, Xiao-Yan |
collection | PubMed |
description | There are three independent molecules in the asymmetric unit of the title compound, C(19)H(16)N(2)O(3), in which the dihedral angles between the naphthalene ring system and the benzene ring are 7.52 (16), 18.15 (18), and 13.9 (2)°. All the molecules exist in the trans configuration with respect to the methylidene units. In each molecule there is one O—H⋯N and one N—H⋯O intramolecular hydrogen bond. In the crystal, two of the molecules are linked via a bifurcated N—H⋯(O,O) hydrogen bond. All three molecules are further linked via C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3201446 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014462011-11-06 N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide Li, Xiao-Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers There are three independent molecules in the asymmetric unit of the title compound, C(19)H(16)N(2)O(3), in which the dihedral angles between the naphthalene ring system and the benzene ring are 7.52 (16), 18.15 (18), and 13.9 (2)°. All the molecules exist in the trans configuration with respect to the methylidene units. In each molecule there is one O—H⋯N and one N—H⋯O intramolecular hydrogen bond. In the crystal, two of the molecules are linked via a bifurcated N—H⋯(O,O) hydrogen bond. All three molecules are further linked via C—H⋯O interactions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201446/ /pubmed/22065731 http://dx.doi.org/10.1107/S1600536811038153 Text en © Xiao-Yan Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Xiao-Yan N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide |
title |
N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide |
title_full |
N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide |
title_fullStr |
N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide |
title_full_unstemmed |
N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide |
title_short |
N′-[(1E)-(2-Hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide |
title_sort | n′-[(1e)-(2-hydroxynaphthalen-1-yl)methylidene]-2-methoxybenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201446/ https://www.ncbi.nlm.nih.gov/pubmed/22065731 http://dx.doi.org/10.1107/S1600536811038153 |
work_keys_str_mv | AT lixiaoyan n1e2hydroxynaphthalen1ylmethylidene2methoxybenzohydrazide |