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2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetrakis(nitrato-κ(2) O,O′)bismuthate(III)
The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyridyl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitrogen atoms from one 2,2′-bipyridine ligand and eight oxy...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201447/ https://www.ncbi.nlm.nih.gov/pubmed/22065819 http://dx.doi.org/10.1107/S160053681103769X |
Sumario: | The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyridyl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitrogen atoms from one 2,2′-bipyridine ligand and eight oxygen atoms from four NO(3) (−) anions. The disordered cation is positioned at the inversion centre. The [Bi(NO(3))(4)(C(10)H(8)N(2))](−) anions and 2-(2-pyridyl)pyridinium cations are connected via N—H⋯O hydrogen bonds into chains. Moreover, these chains are further linked into a two-dimensional layered structure through π–π stacking interactions between bipyridine ligands along the c axis [centroid–centroid distance = 2.868 (4) Å]. |
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