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2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III)

The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyrid­yl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitro­gen atoms from one 2,2′-bipyridine ligand and eight oxy...

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Detalles Bibliográficos
Autores principales: Meng, Zhao-Hui, Zhang, Shu-Shen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201447/
https://www.ncbi.nlm.nih.gov/pubmed/22065819
http://dx.doi.org/10.1107/S160053681103769X
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author Meng, Zhao-Hui
Zhang, Shu-Shen
author_facet Meng, Zhao-Hui
Zhang, Shu-Shen
author_sort Meng, Zhao-Hui
collection PubMed
description The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyrid­yl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitro­gen atoms from one 2,2′-bipyridine ligand and eight oxygen atoms from four NO(3) (−) anions. The disordered cation is positioned at the inversion centre. The [Bi(NO(3))(4)(C(10)H(8)N(2))](−) anions and 2-(2-pyrid­yl)pyridinium cations are connected via N—H⋯O hydrogen bonds into chains. Moreover, these chains are further linked into a two-dimensional layered structure through π–π stacking inter­actions between bipyridine ligands along the c axis [centroid–centroid distance = 2.868 (4) Å].
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spelling pubmed-32014472011-11-06 2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III) Meng, Zhao-Hui Zhang, Shu-Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyrid­yl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitro­gen atoms from one 2,2′-bipyridine ligand and eight oxygen atoms from four NO(3) (−) anions. The disordered cation is positioned at the inversion centre. The [Bi(NO(3))(4)(C(10)H(8)N(2))](−) anions and 2-(2-pyrid­yl)pyridinium cations are connected via N—H⋯O hydrogen bonds into chains. Moreover, these chains are further linked into a two-dimensional layered structure through π–π stacking inter­actions between bipyridine ligands along the c axis [centroid–centroid distance = 2.868 (4) Å]. International Union of Crystallography 2011-09-20 /pmc/articles/PMC3201447/ /pubmed/22065819 http://dx.doi.org/10.1107/S160053681103769X Text en © Meng and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Zhao-Hui
Zhang, Shu-Shen
2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III)
title 2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III)
title_full 2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III)
title_fullStr 2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III)
title_full_unstemmed 2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III)
title_short 2-(2-Pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetra­kis­(nitrato-κ(2) O,O′)bis­muthate(III)
title_sort 2-(2-pyrid­yl)pyridinium (2,2′-bipyridine-κ(2) n,n′)tetra­kis­(nitrato-κ(2) o,o′)bis­muthate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201447/
https://www.ncbi.nlm.nih.gov/pubmed/22065819
http://dx.doi.org/10.1107/S160053681103769X
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