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2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetrakis(nitrato-κ(2) O,O′)bismuthate(III)
The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyridyl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitrogen atoms from one 2,2′-bipyridine ligand and eight oxy...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201447/ https://www.ncbi.nlm.nih.gov/pubmed/22065819 http://dx.doi.org/10.1107/S160053681103769X |
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author | Meng, Zhao-Hui Zhang, Shu-Shen |
author_facet | Meng, Zhao-Hui Zhang, Shu-Shen |
author_sort | Meng, Zhao-Hui |
collection | PubMed |
description | The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyridyl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitrogen atoms from one 2,2′-bipyridine ligand and eight oxygen atoms from four NO(3) (−) anions. The disordered cation is positioned at the inversion centre. The [Bi(NO(3))(4)(C(10)H(8)N(2))](−) anions and 2-(2-pyridyl)pyridinium cations are connected via N—H⋯O hydrogen bonds into chains. Moreover, these chains are further linked into a two-dimensional layered structure through π–π stacking interactions between bipyridine ligands along the c axis [centroid–centroid distance = 2.868 (4) Å]. |
format | Online Article Text |
id | pubmed-3201447 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014472011-11-06 2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetrakis(nitrato-κ(2) O,O′)bismuthate(III) Meng, Zhao-Hui Zhang, Shu-Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyridyl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](−). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitrogen atoms from one 2,2′-bipyridine ligand and eight oxygen atoms from four NO(3) (−) anions. The disordered cation is positioned at the inversion centre. The [Bi(NO(3))(4)(C(10)H(8)N(2))](−) anions and 2-(2-pyridyl)pyridinium cations are connected via N—H⋯O hydrogen bonds into chains. Moreover, these chains are further linked into a two-dimensional layered structure through π–π stacking interactions between bipyridine ligands along the c axis [centroid–centroid distance = 2.868 (4) Å]. International Union of Crystallography 2011-09-20 /pmc/articles/PMC3201447/ /pubmed/22065819 http://dx.doi.org/10.1107/S160053681103769X Text en © Meng and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Meng, Zhao-Hui Zhang, Shu-Shen 2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2) N,N′)tetrakis(nitrato-κ(2) O,O′)bismuthate(III) |
title | 2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2)
N,N′)tetrakis(nitrato-κ(2)
O,O′)bismuthate(III) |
title_full | 2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2)
N,N′)tetrakis(nitrato-κ(2)
O,O′)bismuthate(III) |
title_fullStr | 2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2)
N,N′)tetrakis(nitrato-κ(2)
O,O′)bismuthate(III) |
title_full_unstemmed | 2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2)
N,N′)tetrakis(nitrato-κ(2)
O,O′)bismuthate(III) |
title_short | 2-(2-Pyridyl)pyridinium (2,2′-bipyridine-κ(2)
N,N′)tetrakis(nitrato-κ(2)
O,O′)bismuthate(III) |
title_sort | 2-(2-pyridyl)pyridinium (2,2′-bipyridine-κ(2)
n,n′)tetrakis(nitrato-κ(2)
o,o′)bismuthate(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201447/ https://www.ncbi.nlm.nih.gov/pubmed/22065819 http://dx.doi.org/10.1107/S160053681103769X |
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