Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate

The homoleptic thio­ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa­kis­(thio­ether) octa­hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia­cyclo­nona­ne)...

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Detalles Bibliográficos
Autores principales: Lee, John P., Grant, Gregory J., Noll, Bruce C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201448/
https://www.ncbi.nlm.nih.gov/pubmed/22064382
http://dx.doi.org/10.1107/S1600536811037809
Descripción
Sumario:The homoleptic thio­ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa­kis­(thio­ether) octa­hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia­cyclo­nona­ne), within the unit cell where each Ni(II) lies on an inversion center. In addition to the complex cations, there are two crystallographically independent BF(4) (−) anions present to balance the charge, and each shows disorder along a pseudo-C (3) axis with ratios of 0.53 (2):0.47 (2) and 0.55 (2):0.45 (2). Two nitro­methane solvent mol­ecules per complex cation are also present in the unit cell.

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