Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate

The homoleptic thio­ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa­kis­(thio­ether) octa­hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia­cyclo­nona­ne)...

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Detalles Bibliográficos
Autores principales: Lee, John P., Grant, Gregory J., Noll, Bruce C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201448/
https://www.ncbi.nlm.nih.gov/pubmed/22064382
http://dx.doi.org/10.1107/S1600536811037809
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author Lee, John P.
Grant, Gregory J.
Noll, Bruce C.
author_facet Lee, John P.
Grant, Gregory J.
Noll, Bruce C.
author_sort Lee, John P.
collection PubMed
description The homoleptic thio­ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa­kis­(thio­ether) octa­hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia­cyclo­nona­ne), within the unit cell where each Ni(II) lies on an inversion center. In addition to the complex cations, there are two crystallographically independent BF(4) (−) anions present to balance the charge, and each shows disorder along a pseudo-C (3) axis with ratios of 0.53 (2):0.47 (2) and 0.55 (2):0.45 (2). Two nitro­methane solvent mol­ecules per complex cation are also present in the unit cell.
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spelling pubmed-32014482011-11-06 Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate Lee, John P. Grant, Gregory J. Noll, Bruce C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The homoleptic thio­ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa­kis­(thio­ether) octa­hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia­cyclo­nona­ne), within the unit cell where each Ni(II) lies on an inversion center. In addition to the complex cations, there are two crystallographically independent BF(4) (−) anions present to balance the charge, and each shows disorder along a pseudo-C (3) axis with ratios of 0.53 (2):0.47 (2) and 0.55 (2):0.45 (2). Two nitro­methane solvent mol­ecules per complex cation are also present in the unit cell. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201448/ /pubmed/22064382 http://dx.doi.org/10.1107/S1600536811037809 Text en © Lee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, John P.
Grant, Gregory J.
Noll, Bruce C.
Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate
title Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate
title_full Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate
title_fullStr Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate
title_full_unstemmed Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate
title_short Bis(1,4,7-trithia­cyclo­nona­ne)nickel(II) bis­(tetra­fluorido­borate) nitro­methane disolvate
title_sort bis(1,4,7-trithia­cyclo­nona­ne)nickel(ii) bis­(tetra­fluorido­borate) nitro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201448/
https://www.ncbi.nlm.nih.gov/pubmed/22064382
http://dx.doi.org/10.1107/S1600536811037809
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AT nollbrucec bis147trithiacyclononanenickeliibistetrafluoridoboratenitromethanedisolvate

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