Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate

In the title compound, [Zn(C(12)H(6)N(2)O(2))(3)](ClO(4))(2)·CH(3)CN, the Zn(II) atom is coordinated by six N atoms from three chelating 1,10-phenanthroline-5,6-dione ligands in a distorted octa­hedral environment. In the crystal, inter­molecular C—H⋯O hydrogen bonds and O⋯π and N⋯π inter­actions [O...

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Detalles Bibliográficos
Autores principales: Zhao, Jing, Zhang, Heng, Zhang, Zhaozhi, Zhao, Haiyan, Zhu, Guoyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201451/
https://www.ncbi.nlm.nih.gov/pubmed/22064769
http://dx.doi.org/10.1107/S1600536811037081
Descripción
Sumario:In the title compound, [Zn(C(12)H(6)N(2)O(2))(3)](ClO(4))(2)·CH(3)CN, the Zn(II) atom is coordinated by six N atoms from three chelating 1,10-phenanthroline-5,6-dione ligands in a distorted octa­hedral environment. In the crystal, inter­molecular C—H⋯O hydrogen bonds and O⋯π and N⋯π inter­actions [O⋯centroid distances = 2.907 (5) and 2.843 (7) Å; N⋯centroid distance = 2.861 (10) Å] link the complex cations, perchlorate anions and acetonitrile solvent mol­ecules into a three-dimensional network.

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