Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate

In the title compound, [Zn(C(12)H(6)N(2)O(2))(3)](ClO(4))(2)·CH(3)CN, the Zn(II) atom is coordinated by six N atoms from three chelating 1,10-phenanthroline-5,6-dione ligands in a distorted octa­hedral environment. In the crystal, inter­molecular C—H⋯O hydrogen bonds and O⋯π and N⋯π inter­actions [O...

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Autores principales: Zhao, Jing, Zhang, Heng, Zhang, Zhaozhi, Zhao, Haiyan, Zhu, Guoyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201451/
https://www.ncbi.nlm.nih.gov/pubmed/22064769
http://dx.doi.org/10.1107/S1600536811037081
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author Zhao, Jing
Zhang, Heng
Zhang, Zhaozhi
Zhao, Haiyan
Zhu, Guoyi
author_facet Zhao, Jing
Zhang, Heng
Zhang, Zhaozhi
Zhao, Haiyan
Zhu, Guoyi
author_sort Zhao, Jing
collection PubMed
description In the title compound, [Zn(C(12)H(6)N(2)O(2))(3)](ClO(4))(2)·CH(3)CN, the Zn(II) atom is coordinated by six N atoms from three chelating 1,10-phenanthroline-5,6-dione ligands in a distorted octa­hedral environment. In the crystal, inter­molecular C—H⋯O hydrogen bonds and O⋯π and N⋯π inter­actions [O⋯centroid distances = 2.907 (5) and 2.843 (7) Å; N⋯centroid distance = 2.861 (10) Å] link the complex cations, perchlorate anions and acetonitrile solvent mol­ecules into a three-dimensional network.
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spelling pubmed-32014512011-11-06 Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate Zhao, Jing Zhang, Heng Zhang, Zhaozhi Zhao, Haiyan Zhu, Guoyi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(12)H(6)N(2)O(2))(3)](ClO(4))(2)·CH(3)CN, the Zn(II) atom is coordinated by six N atoms from three chelating 1,10-phenanthroline-5,6-dione ligands in a distorted octa­hedral environment. In the crystal, inter­molecular C—H⋯O hydrogen bonds and O⋯π and N⋯π inter­actions [O⋯centroid distances = 2.907 (5) and 2.843 (7) Å; N⋯centroid distance = 2.861 (10) Å] link the complex cations, perchlorate anions and acetonitrile solvent mol­ecules into a three-dimensional network. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201451/ /pubmed/22064769 http://dx.doi.org/10.1107/S1600536811037081 Text en © Zhao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Jing
Zhang, Heng
Zhang, Zhaozhi
Zhao, Haiyan
Zhu, Guoyi
Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate
title Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate
title_full Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate
title_fullStr Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate
title_full_unstemmed Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate
title_short Tris(1,10-phenanthroline-5,6-dione-κ(2) N,N′)zinc bis­(perchlorate) acetonitrile monosolvate
title_sort tris(1,10-phenanthroline-5,6-dione-κ(2) n,n′)zinc bis­(perchlorate) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201451/
https://www.ncbi.nlm.nih.gov/pubmed/22064769
http://dx.doi.org/10.1107/S1600536811037081
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