1-(2,4,6-Triisopropyl­phen­yl)ethanone

The title compound, C(17)H(26)O, is a di-ortho-alkyl substituted phenyl ethanone that exhibits a significant twisting of the ketone fragment relative to the aromatic ring [O—C—C—C torsion angle = 89.32 (17)°] due to steric pressure from the ortho-isopropyl groups. One ortho- and the para-isopropyl g...

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Detalles Bibliográficos
Autores principales: Blair, Amber D., Hendsbee, Arthur D., Masuda, Jason D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201453/
https://www.ncbi.nlm.nih.gov/pubmed/22064822
http://dx.doi.org/10.1107/S1600536811038293
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author Blair, Amber D.
Hendsbee, Arthur D.
Masuda, Jason D.
author_facet Blair, Amber D.
Hendsbee, Arthur D.
Masuda, Jason D.
author_sort Blair, Amber D.
collection PubMed
description The title compound, C(17)H(26)O, is a di-ortho-alkyl substituted phenyl ethanone that exhibits a significant twisting of the ketone fragment relative to the aromatic ring [O—C—C—C torsion angle = 89.32 (17)°] due to steric pressure from the ortho-isopropyl groups. One ortho- and the para-isopropyl group exhibit orientational disorder with a refined site occupancy factor of 0.562 (3):0.438 (3).
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spelling pubmed-32014532011-11-06 1-(2,4,6-Triisopropyl­phen­yl)ethanone Blair, Amber D. Hendsbee, Arthur D. Masuda, Jason D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(26)O, is a di-ortho-alkyl substituted phenyl ethanone that exhibits a significant twisting of the ketone fragment relative to the aromatic ring [O—C—C—C torsion angle = 89.32 (17)°] due to steric pressure from the ortho-isopropyl groups. One ortho- and the para-isopropyl group exhibit orientational disorder with a refined site occupancy factor of 0.562 (3):0.438 (3). International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201453/ /pubmed/22064822 http://dx.doi.org/10.1107/S1600536811038293 Text en © Blair et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Blair, Amber D.
Hendsbee, Arthur D.
Masuda, Jason D.
1-(2,4,6-Triisopropyl­phen­yl)ethanone
title 1-(2,4,6-Triisopropyl­phen­yl)ethanone
title_full 1-(2,4,6-Triisopropyl­phen­yl)ethanone
title_fullStr 1-(2,4,6-Triisopropyl­phen­yl)ethanone
title_full_unstemmed 1-(2,4,6-Triisopropyl­phen­yl)ethanone
title_short 1-(2,4,6-Triisopropyl­phen­yl)ethanone
title_sort 1-(2,4,6-triisopropyl­phen­yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201453/
https://www.ncbi.nlm.nih.gov/pubmed/22064822
http://dx.doi.org/10.1107/S1600536811038293
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