Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate

The title compound, [Sn(C(6)H(5))(2)(C(12)H(11)N(4)S(2))Cl]·CH(4)O, is formed during the reaction between 2-acetyl­thia­zole 4-phenyl­thio­semicarbazone (Hacthptsc) and diphenyl­tin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octa­hedral geometry with the [N(2)S] an...

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Autores principales: Arumugam, Sri Ranjini, Dasary, Samuel S. R., Venkatraman, Ramaiyer, Yu, Hongtao, Fronczek, Frank R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201461/
https://www.ncbi.nlm.nih.gov/pubmed/22065366
http://dx.doi.org/10.1107/S1600536811037627
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author Arumugam, Sri Ranjini
Dasary, Samuel S. R.
Venkatraman, Ramaiyer
Yu, Hongtao
Fronczek, Frank R.
author_facet Arumugam, Sri Ranjini
Dasary, Samuel S. R.
Venkatraman, Ramaiyer
Yu, Hongtao
Fronczek, Frank R.
author_sort Arumugam, Sri Ranjini
collection PubMed
description The title compound, [Sn(C(6)H(5))(2)(C(12)H(11)N(4)S(2))Cl]·CH(4)O, is formed during the reaction between 2-acetyl­thia­zole 4-phenyl­thio­semicarbazone (Hacthptsc) and diphenyl­tin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octa­hedral geometry with the [N(2)S] anionic tridentate thio­semicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn—Cl distance is 2.5929 (6), Sn—S is 2.4896 (6) and Sn—N to the central N is 2.3220 (16) Å. The MeOH mol­ecules link the Sn complexes into one-dimensional chains via N—H⋯O and O—H⋯Cl hydrogen bonds.
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spelling pubmed-32014612011-11-06 Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate Arumugam, Sri Ranjini Dasary, Samuel S. R. Venkatraman, Ramaiyer Yu, Hongtao Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(6)H(5))(2)(C(12)H(11)N(4)S(2))Cl]·CH(4)O, is formed during the reaction between 2-acetyl­thia­zole 4-phenyl­thio­semicarbazone (Hacthptsc) and diphenyl­tin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octa­hedral geometry with the [N(2)S] anionic tridentate thio­semicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn—Cl distance is 2.5929 (6), Sn—S is 2.4896 (6) and Sn—N to the central N is 2.3220 (16) Å. The MeOH mol­ecules link the Sn complexes into one-dimensional chains via N—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201461/ /pubmed/22065366 http://dx.doi.org/10.1107/S1600536811037627 Text en © Arumugam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arumugam, Sri Ranjini
Dasary, Samuel S. R.
Venkatraman, Ramaiyer
Yu, Hongtao
Fronczek, Frank R.
Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate
title Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate
title_full Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate
title_fullStr Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate
title_full_unstemmed Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate
title_short Chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κN)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) N (1),S}tin(IV) methanol monosolvate
title_sort chloridodiphen­yl{[1-(1,3-thia­zol-2-yl-κn)ethyl­idene]-4-phenyl­thio­semicarbazidato-κ(2) n (1),s}tin(iv) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201461/
https://www.ncbi.nlm.nih.gov/pubmed/22065366
http://dx.doi.org/10.1107/S1600536811037627
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