Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II)

In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo­octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol­ecules that complete the coordination sphere f...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201466/
https://www.ncbi.nlm.nih.gov/pubmed/22058687
http://dx.doi.org/10.1107/S1600536811035380
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author Chiririwa, Haleden
Meijboom, Reinout
author_facet Chiririwa, Haleden
Meijboom, Reinout
author_sort Chiririwa, Haleden
collection PubMed
description In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo­octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol­ecules that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered octa­hedral with slight trigonal distortion. The three C atoms of one of the acrylonitrile ligands are disordered over two sets of sites in a 0.581 (13):0.419 (13) ratio.
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spelling pubmed-32014662011-11-06 Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) Chiririwa, Haleden Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo­octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol­ecules that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered octa­hedral with slight trigonal distortion. The three C atoms of one of the acrylonitrile ligands are disordered over two sets of sites in a 0.581 (13):0.419 (13) ratio. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201466/ /pubmed/22058687 http://dx.doi.org/10.1107/S1600536811035380 Text en © Chiririwa and Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Meijboom, Reinout
Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II)
title Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II)
title_full Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II)
title_fullStr Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II)
title_full_unstemmed Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II)
title_short Bis(acrylonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II)
title_sort bis(acrylonitrile-κn)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201466/
https://www.ncbi.nlm.nih.gov/pubmed/22058687
http://dx.doi.org/10.1107/S1600536811035380
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AT meijboomreinout bisacrylonitrilekndichloridoē4cycloocta15dienerutheniumii

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