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(3Z)-3-Hydrazinylideneindolin-2-one
The title molecule, C(8)H(7)N(3)O, is almost planar, with a maximum deviation of 0.0232 (2) Å from the least-squares plane. The Z conformation of the C=N double bond is stabilized by an intramolecular N—H⋯O hydrogen bond. In the crystal, adjacent molecules are linked by intermolecular N—H⋯N and...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201467/ https://www.ncbi.nlm.nih.gov/pubmed/22058742 http://dx.doi.org/10.1107/S1600536811035367 |
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author | Ara Jamal, Rifat Ashiq, Uzma Yousuf, Sammer |
author_facet | Ara Jamal, Rifat Ashiq, Uzma Yousuf, Sammer |
author_sort | Ara Jamal, Rifat |
collection | PubMed |
description | The title molecule, C(8)H(7)N(3)O, is almost planar, with a maximum deviation of 0.0232 (2) Å from the least-squares plane. The Z conformation of the C=N double bond is stabilized by an intramolecular N—H⋯O hydrogen bond. In the crystal, adjacent molecules are linked by intermolecular N—H⋯N and N—H⋯O hydrogen bonds, forming zigzag sheets parallel to the c axis; the sheets are further stabilized by π–π interactions [centroid–centroid distance = 3.7390 (10) Å]. |
format | Online Article Text |
id | pubmed-3201467 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014672011-11-06 (3Z)-3-Hydrazinylideneindolin-2-one Ara Jamal, Rifat Ashiq, Uzma Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(8)H(7)N(3)O, is almost planar, with a maximum deviation of 0.0232 (2) Å from the least-squares plane. The Z conformation of the C=N double bond is stabilized by an intramolecular N—H⋯O hydrogen bond. In the crystal, adjacent molecules are linked by intermolecular N—H⋯N and N—H⋯O hydrogen bonds, forming zigzag sheets parallel to the c axis; the sheets are further stabilized by π–π interactions [centroid–centroid distance = 3.7390 (10) Å]. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201467/ /pubmed/22058742 http://dx.doi.org/10.1107/S1600536811035367 Text en © Ara Jamal et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ara Jamal, Rifat Ashiq, Uzma Yousuf, Sammer (3Z)-3-Hydrazinylideneindolin-2-one |
title | (3Z)-3-Hydrazinylideneindolin-2-one |
title_full | (3Z)-3-Hydrazinylideneindolin-2-one |
title_fullStr | (3Z)-3-Hydrazinylideneindolin-2-one |
title_full_unstemmed | (3Z)-3-Hydrazinylideneindolin-2-one |
title_short | (3Z)-3-Hydrazinylideneindolin-2-one |
title_sort | (3z)-3-hydrazinylideneindolin-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201467/ https://www.ncbi.nlm.nih.gov/pubmed/22058742 http://dx.doi.org/10.1107/S1600536811035367 |
work_keys_str_mv | AT arajamalrifat 3z3hydrazinylideneindolin2one AT ashiquzma 3z3hydrazinylideneindolin2one AT yousufsammer 3z3hydrazinylideneindolin2one |