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(3Z)-3-Hydrazinylideneindolin-2-one

The title mol­ecule, C(8)H(7)N(3)O, is almost planar, with a maximum deviation of 0.0232 (2) Å from the least-squares plane. The Z conformation of the C=N double bond is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, adjacent mol­ecules are linked by inter­molecular N—H⋯N and...

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Detalles Bibliográficos
Autores principales: Ara Jamal, Rifat, Ashiq, Uzma, Yousuf, Sammer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201467/
https://www.ncbi.nlm.nih.gov/pubmed/22058742
http://dx.doi.org/10.1107/S1600536811035367
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author Ara Jamal, Rifat
Ashiq, Uzma
Yousuf, Sammer
author_facet Ara Jamal, Rifat
Ashiq, Uzma
Yousuf, Sammer
author_sort Ara Jamal, Rifat
collection PubMed
description The title mol­ecule, C(8)H(7)N(3)O, is almost planar, with a maximum deviation of 0.0232 (2) Å from the least-squares plane. The Z conformation of the C=N double bond is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, adjacent mol­ecules are linked by inter­molecular N—H⋯N and N—H⋯O hydrogen bonds, forming zigzag sheets parallel to the c axis; the sheets are further stabilized by π–π inter­actions [centroid–centroid distance = 3.7390 (10) Å].
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spelling pubmed-32014672011-11-06 (3Z)-3-Hydrazinylideneindolin-2-one Ara Jamal, Rifat Ashiq, Uzma Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(8)H(7)N(3)O, is almost planar, with a maximum deviation of 0.0232 (2) Å from the least-squares plane. The Z conformation of the C=N double bond is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, adjacent mol­ecules are linked by inter­molecular N—H⋯N and N—H⋯O hydrogen bonds, forming zigzag sheets parallel to the c axis; the sheets are further stabilized by π–π inter­actions [centroid–centroid distance = 3.7390 (10) Å]. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201467/ /pubmed/22058742 http://dx.doi.org/10.1107/S1600536811035367 Text en © Ara Jamal et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ara Jamal, Rifat
Ashiq, Uzma
Yousuf, Sammer
(3Z)-3-Hydrazinylideneindolin-2-one
title (3Z)-3-Hydrazinylideneindolin-2-one
title_full (3Z)-3-Hydrazinylideneindolin-2-one
title_fullStr (3Z)-3-Hydrazinylideneindolin-2-one
title_full_unstemmed (3Z)-3-Hydrazinylideneindolin-2-one
title_short (3Z)-3-Hydrazinylideneindolin-2-one
title_sort (3z)-3-hydrazinylideneindolin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201467/
https://www.ncbi.nlm.nih.gov/pubmed/22058742
http://dx.doi.org/10.1107/S1600536811035367
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