(4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V)

In the title mononuclear dioxidovanadium(V) complex, [V(C(13)H(16)BrN(2)O(2))O(2)], the V(V) atom is five-coordinated by one phenolate O, one imine N and one morpholine N atom of the Schiff base ligand, and by two oxide O atoms, forming a distorted square-pyramidal geometry. In the crystal, weak C—H...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Wu, Xiang, Cao, Feng, Yuan, Cai-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201471/
https://www.ncbi.nlm.nih.gov/pubmed/22065600
http://dx.doi.org/10.1107/S1600536811035240
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author Wang, Chen-Yi
Wu, Xiang
Cao, Feng
Yuan, Cai-Jun
author_facet Wang, Chen-Yi
Wu, Xiang
Cao, Feng
Yuan, Cai-Jun
author_sort Wang, Chen-Yi
collection PubMed
description In the title mononuclear dioxidovanadium(V) complex, [V(C(13)H(16)BrN(2)O(2))O(2)], the V(V) atom is five-coordinated by one phenolate O, one imine N and one morpholine N atom of the Schiff base ligand, and by two oxide O atoms, forming a distorted square-pyramidal geometry. In the crystal, weak C—H⋯O inter­actions and a short Br⋯Br contact [3.4597 (12) Å] are observed.
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spelling pubmed-32014712011-11-06 (4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V) Wang, Chen-Yi Wu, Xiang Cao, Feng Yuan, Cai-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear dioxidovanadium(V) complex, [V(C(13)H(16)BrN(2)O(2))O(2)], the V(V) atom is five-coordinated by one phenolate O, one imine N and one morpholine N atom of the Schiff base ligand, and by two oxide O atoms, forming a distorted square-pyramidal geometry. In the crystal, weak C—H⋯O inter­actions and a short Br⋯Br contact [3.4597 (12) Å] are observed. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201471/ /pubmed/22065600 http://dx.doi.org/10.1107/S1600536811035240 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Wu, Xiang
Cao, Feng
Yuan, Cai-Jun
(4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V)
title (4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V)
title_full (4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V)
title_fullStr (4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V)
title_full_unstemmed (4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V)
title_short (4-Bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(V)
title_sort (4-bromo-2-{[2-(morpholin-4-yl)ethyl­imino]­meth­yl}phenolato)dioxido­vanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201471/
https://www.ncbi.nlm.nih.gov/pubmed/22065600
http://dx.doi.org/10.1107/S1600536811035240
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