2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone

In the title compound, C(15)H(9)Cl(2)N(3)O, an intra­molecular C—H⋯O inter­action generates an S(7) ring motif. The cyclo­penta-1,3-diene ring forms dihedral angles of 1.93 (6) and 2.78 (6)° with its attached benzene rings. In the crystal, mol­ecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, the...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Kayarmar, Reshma, Dinesha, Nagaraja, G. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201472/
https://www.ncbi.nlm.nih.gov/pubmed/22058777
http://dx.doi.org/10.1107/S1600536811036762
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author Fun, Hoong-Kun
Chia, Tze Shyang
Kayarmar, Reshma
Dinesha,
Nagaraja, G. K.
author_facet Fun, Hoong-Kun
Chia, Tze Shyang
Kayarmar, Reshma
Dinesha,
Nagaraja, G. K.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(15)H(9)Cl(2)N(3)O, an intra­molecular C—H⋯O inter­action generates an S(7) ring motif. The cyclo­penta-1,3-diene ring forms dihedral angles of 1.93 (6) and 2.78 (6)° with its attached benzene rings. In the crystal, mol­ecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, thereby forming layers lying parallel to the ac plane. The crystal also features a π–π inter­action with a centroid–centroid distance of 3.5612 (6) Å.
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spelling pubmed-32014722011-11-06 2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone Fun, Hoong-Kun Chia, Tze Shyang Kayarmar, Reshma Dinesha, Nagaraja, G. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(9)Cl(2)N(3)O, an intra­molecular C—H⋯O inter­action generates an S(7) ring motif. The cyclo­penta-1,3-diene ring forms dihedral angles of 1.93 (6) and 2.78 (6)° with its attached benzene rings. In the crystal, mol­ecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, thereby forming layers lying parallel to the ac plane. The crystal also features a π–π inter­action with a centroid–centroid distance of 3.5612 (6) Å. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201472/ /pubmed/22058777 http://dx.doi.org/10.1107/S1600536811036762 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chia, Tze Shyang
Kayarmar, Reshma
Dinesha,
Nagaraja, G. K.
2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone
title 2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone
title_full 2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone
title_fullStr 2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone
title_full_unstemmed 2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone
title_short 2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone
title_sort 2-azido-1-(3,6-dichloro-9h-fluoren-1-yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201472/
https://www.ncbi.nlm.nih.gov/pubmed/22058777
http://dx.doi.org/10.1107/S1600536811036762
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