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(Acetylacetonato-κ(2) O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2) C (1),N]iridium(III)
In the title compound, [Ir(C(18)H(12)NO(2))(2)(C(5)H(7)O(2))], the Ir atom is O,O′-chelated by the acetylacetonate group and C,N-chelated by the 2-arylnaphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octahedral geometry. Intramolecular C—H⋯O hydrogen bonds occur. I...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201473/ https://www.ncbi.nlm.nih.gov/pubmed/22065644 http://dx.doi.org/10.1107/S1600536811035690 |
| _version_ | 1782214882501853184 |
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| author | Li, Song Yin, Guo-Jie Wang, Shi-Min Zhou, Yuan-Yuan |
| author_facet | Li, Song Yin, Guo-Jie Wang, Shi-Min Zhou, Yuan-Yuan |
| author_sort | Li, Song |
| collection | PubMed |
| description | In the title compound, [Ir(C(18)H(12)NO(2))(2)(C(5)H(7)O(2))], the Ir atom is O,O′-chelated by the acetylacetonate group and C,N-chelated by the 2-arylnaphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octahedral geometry. Intramolecular C—H⋯O hydrogen bonds occur. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into columns parallel to the b axis. |
| format | Online Article Text |
| id | pubmed-3201473 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32014732011-11-06 (Acetylacetonato-κ(2) O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2) C (1),N]iridium(III) Li, Song Yin, Guo-Jie Wang, Shi-Min Zhou, Yuan-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(18)H(12)NO(2))(2)(C(5)H(7)O(2))], the Ir atom is O,O′-chelated by the acetylacetonate group and C,N-chelated by the 2-arylnaphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octahedral geometry. Intramolecular C—H⋯O hydrogen bonds occur. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into columns parallel to the b axis. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201473/ /pubmed/22065644 http://dx.doi.org/10.1107/S1600536811035690 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Song Yin, Guo-Jie Wang, Shi-Min Zhou, Yuan-Yuan (Acetylacetonato-κ(2) O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2) C (1),N]iridium(III) |
| title | (Acetylacetonato-κ(2)
O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_full | (Acetylacetonato-κ(2)
O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_fullStr | (Acetylacetonato-κ(2)
O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_full_unstemmed | (Acetylacetonato-κ(2)
O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_short | (Acetylacetonato-κ(2)
O,O′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_sort | (acetylacetonato-κ(2)
o,o′)bis[5-methoxy-2-(naphth[1,2-d][1,3]oxazol-2-yl)phenyl-κ(2)
c
(1),n]iridium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201473/ https://www.ncbi.nlm.nih.gov/pubmed/22065644 http://dx.doi.org/10.1107/S1600536811035690 |
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