11α,15α-Dihy­droxy­androst-4-ene-3,17-dione

The title compound, C(19)H(26)O(4), was biotransformed from androstenedione. In the crystal, inter­molecular O—H⋯O hydrogen bonds link molecules into a corrugated sheet, which lies parallel to the ab plane. Ring A has a slightly distorted half-chair conformation, rings B and C adopt chair conformati...

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Detalles Bibliográficos
Autores principales: Shen, Yan-Bing, Wang, Min, Liang, Qi-Kun, Luo, Jian-Mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201477/
https://www.ncbi.nlm.nih.gov/pubmed/22058810
http://dx.doi.org/10.1107/S1600536811038608
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author Shen, Yan-Bing
Wang, Min
Liang, Qi-Kun
Luo, Jian-Mei
author_facet Shen, Yan-Bing
Wang, Min
Liang, Qi-Kun
Luo, Jian-Mei
author_sort Shen, Yan-Bing
collection PubMed
description The title compound, C(19)H(26)O(4), was biotransformed from androstenedione. In the crystal, inter­molecular O—H⋯O hydrogen bonds link molecules into a corrugated sheet, which lies parallel to the ab plane. Ring A has a slightly distorted half-chair conformation, rings B and C adopt chair conformations, while the cyclo­pentane ring D adopts a 14α-envelope conformation.
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spelling pubmed-32014772011-11-06 11α,15α-Dihy­droxy­androst-4-ene-3,17-dione Shen, Yan-Bing Wang, Min Liang, Qi-Kun Luo, Jian-Mei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(26)O(4), was biotransformed from androstenedione. In the crystal, inter­molecular O—H⋯O hydrogen bonds link molecules into a corrugated sheet, which lies parallel to the ab plane. Ring A has a slightly distorted half-chair conformation, rings B and C adopt chair conformations, while the cyclo­pentane ring D adopts a 14α-envelope conformation. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201477/ /pubmed/22058810 http://dx.doi.org/10.1107/S1600536811038608 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shen, Yan-Bing
Wang, Min
Liang, Qi-Kun
Luo, Jian-Mei
11α,15α-Dihy­droxy­androst-4-ene-3,17-dione
title 11α,15α-Dihy­droxy­androst-4-ene-3,17-dione
title_full 11α,15α-Dihy­droxy­androst-4-ene-3,17-dione
title_fullStr 11α,15α-Dihy­droxy­androst-4-ene-3,17-dione
title_full_unstemmed 11α,15α-Dihy­droxy­androst-4-ene-3,17-dione
title_short 11α,15α-Dihy­droxy­androst-4-ene-3,17-dione
title_sort 11α,15α-dihy­droxy­androst-4-ene-3,17-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201477/
https://www.ncbi.nlm.nih.gov/pubmed/22058810
http://dx.doi.org/10.1107/S1600536811038608
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