(E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline

In the title molecule, C(21)H(14)N(2)O(2), the anthracenyl system is approximately planar [maximum deviation = 0.056 (4) Å] and is oriented at a dihedral angle of 73.6 (1)° with respect to the benzene ring. An intra­molecular C—H⋯N hydrogen bond generates an S(6) ring motif. The crystal packing is s...

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Detalles Bibliográficos
Autores principales: Geetha, K., Kumar, D. K. Andrew Prasanna, Lakshmanan, D., Savitha, R., Murugavel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201478/
https://www.ncbi.nlm.nih.gov/pubmed/22058743
http://dx.doi.org/10.1107/S1600536811035859
Descripción
Sumario:In the title molecule, C(21)H(14)N(2)O(2), the anthracenyl system is approximately planar [maximum deviation = 0.056 (4) Å] and is oriented at a dihedral angle of 73.6 (1)° with respect to the benzene ring. An intra­molecular C—H⋯N hydrogen bond generates an S(6) ring motif. The crystal packing is stabilized by C—H⋯π and π–π inter­actions [centroid–centroid distances of 3.688 (2), 3.656 (1) and 3.716 (2) Å].

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