(E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline

In the title molecule, C(21)H(14)N(2)O(2), the anthracenyl system is approximately planar [maximum deviation = 0.056 (4) Å] and is oriented at a dihedral angle of 73.6 (1)° with respect to the benzene ring. An intra­molecular C—H⋯N hydrogen bond generates an S(6) ring motif. The crystal packing is s...

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Detalles Bibliográficos
Autores principales: Geetha, K., Kumar, D. K. Andrew Prasanna, Lakshmanan, D., Savitha, R., Murugavel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201478/
https://www.ncbi.nlm.nih.gov/pubmed/22058743
http://dx.doi.org/10.1107/S1600536811035859
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author Geetha, K.
Kumar, D. K. Andrew Prasanna
Lakshmanan, D.
Savitha, R.
Murugavel, S.
author_facet Geetha, K.
Kumar, D. K. Andrew Prasanna
Lakshmanan, D.
Savitha, R.
Murugavel, S.
author_sort Geetha, K.
collection PubMed
description In the title molecule, C(21)H(14)N(2)O(2), the anthracenyl system is approximately planar [maximum deviation = 0.056 (4) Å] and is oriented at a dihedral angle of 73.6 (1)° with respect to the benzene ring. An intra­molecular C—H⋯N hydrogen bond generates an S(6) ring motif. The crystal packing is stabilized by C—H⋯π and π–π inter­actions [centroid–centroid distances of 3.688 (2), 3.656 (1) and 3.716 (2) Å].
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spelling pubmed-32014782011-11-06 (E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline Geetha, K. Kumar, D. K. Andrew Prasanna Lakshmanan, D. Savitha, R. Murugavel, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(21)H(14)N(2)O(2), the anthracenyl system is approximately planar [maximum deviation = 0.056 (4) Å] and is oriented at a dihedral angle of 73.6 (1)° with respect to the benzene ring. An intra­molecular C—H⋯N hydrogen bond generates an S(6) ring motif. The crystal packing is stabilized by C—H⋯π and π–π inter­actions [centroid–centroid distances of 3.688 (2), 3.656 (1) and 3.716 (2) Å]. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201478/ /pubmed/22058743 http://dx.doi.org/10.1107/S1600536811035859 Text en © Geetha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Geetha, K.
Kumar, D. K. Andrew Prasanna
Lakshmanan, D.
Savitha, R.
Murugavel, S.
(E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline
title (E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline
title_full (E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline
title_fullStr (E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline
title_full_unstemmed (E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline
title_short (E)-N-(Anthracen-9-yl­methyl­idene)-4-nitro­aniline
title_sort (e)-n-(anthracen-9-yl­methyl­idene)-4-nitro­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201478/
https://www.ncbi.nlm.nih.gov/pubmed/22058743
http://dx.doi.org/10.1107/S1600536811035859
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