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2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole

In the title compound, C(17)H(11)N(5)S(2), the dihedral angles formed between the triazole ring and the benzene ring and the 1,3-benzothia­zole ring system are 8.67 (8) and 13.90 (9)°, respectively. The conformation of the triazolo-thia­diazin-3-yl fused ring system is a twisted half-chair. Overall,...

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Detalles Bibliográficos
Autores principales: Abdel-Aziz, Hatem A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201480/
https://www.ncbi.nlm.nih.gov/pubmed/22058756
http://dx.doi.org/10.1107/S1600536811036452
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author Abdel-Aziz, Hatem A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Abdel-Aziz, Hatem A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description In the title compound, C(17)H(11)N(5)S(2), the dihedral angles formed between the triazole ring and the benzene ring and the 1,3-benzothia­zole ring system are 8.67 (8) and 13.90 (9)°, respectively. The conformation of the triazolo-thia­diazin-3-yl fused ring system is a twisted half-chair. Overall, the mol­ecule adopts a flattened shape. Supra­molecular helical chains along the a axis sustained by C—H⋯N inter­actions are found in the crystal structure. These are linked via C—H⋯π contacts as well as π–π [centroid–centroid distance = 3.5911 (12) Å] inter­actions between the triazole and thia­zole rings.
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spelling pubmed-32014802011-11-06 2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole Abdel-Aziz, Hatem A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(11)N(5)S(2), the dihedral angles formed between the triazole ring and the benzene ring and the 1,3-benzothia­zole ring system are 8.67 (8) and 13.90 (9)°, respectively. The conformation of the triazolo-thia­diazin-3-yl fused ring system is a twisted half-chair. Overall, the mol­ecule adopts a flattened shape. Supra­molecular helical chains along the a axis sustained by C—H⋯N inter­actions are found in the crystal structure. These are linked via C—H⋯π contacts as well as π–π [centroid–centroid distance = 3.5911 (12) Å] inter­actions between the triazole and thia­zole rings. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201480/ /pubmed/22058756 http://dx.doi.org/10.1107/S1600536811036452 Text en © Abdel-Aziz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Ng, Seik Weng
Tiekink, Edward R. T.
2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole
title 2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole
title_full 2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole
title_fullStr 2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole
title_full_unstemmed 2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole
title_short 2-(6-Phenyl-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole
title_sort 2-(6-phenyl-7h-1,2,4-triazolo[3,4-b][1,3,4]thia­diazin-3-yl)-1,3-benzothia­zole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201480/
https://www.ncbi.nlm.nih.gov/pubmed/22058756
http://dx.doi.org/10.1107/S1600536811036452
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