4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate

The title compound {systematic name: 4-[bis(4-fluorophenyl)methyl]piperazin-1-ium 2,4,6-tri­nitro­phenolate}, C(17)H(19)F(2)N(2) (+)·C(6)H(2)N(3)O(7) (−), is the picrate salt of a piperazine-supported amine bearing a benzhydryl substituent on one of its N atoms. During co-crystallisation, protonatio...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas, Hosten, Eric, Dayananda, Alaloor S., Yathirajan, Hemmige S., Narayana, Badiadka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201484/
https://www.ncbi.nlm.nih.gov/pubmed/22064439
http://dx.doi.org/10.1107/S160053681103580X
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author Betz, Richard
Gerber, Thomas
Hosten, Eric
Dayananda, Alaloor S.
Yathirajan, Hemmige S.
Narayana, Badiadka
author_facet Betz, Richard
Gerber, Thomas
Hosten, Eric
Dayananda, Alaloor S.
Yathirajan, Hemmige S.
Narayana, Badiadka
author_sort Betz, Richard
collection PubMed
description The title compound {systematic name: 4-[bis(4-fluorophenyl)methyl]piperazin-1-ium 2,4,6-tri­nitro­phenolate}, C(17)H(19)F(2)N(2) (+)·C(6)H(2)N(3)O(7) (−), is the picrate salt of a piperazine-supported amine bearing a benzhydryl substituent on one of its N atoms. During co-crystallisation, protonation took place on the N atom of the secondary amine functionality. The non-aromatic six-membered heterocycle adopts a chair conformation. In the crystal, N—H⋯O hydrogen bonds as well as C—H⋯O contacts connect the components into a three-dimensional network.
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spelling pubmed-32014842011-11-06 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate Betz, Richard Gerber, Thomas Hosten, Eric Dayananda, Alaloor S. Yathirajan, Hemmige S. Narayana, Badiadka Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound {systematic name: 4-[bis(4-fluorophenyl)methyl]piperazin-1-ium 2,4,6-tri­nitro­phenolate}, C(17)H(19)F(2)N(2) (+)·C(6)H(2)N(3)O(7) (−), is the picrate salt of a piperazine-supported amine bearing a benzhydryl substituent on one of its N atoms. During co-crystallisation, protonation took place on the N atom of the secondary amine functionality. The non-aromatic six-membered heterocycle adopts a chair conformation. In the crystal, N—H⋯O hydrogen bonds as well as C—H⋯O contacts connect the components into a three-dimensional network. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201484/ /pubmed/22064439 http://dx.doi.org/10.1107/S160053681103580X Text en © Betz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
Gerber, Thomas
Hosten, Eric
Dayananda, Alaloor S.
Yathirajan, Hemmige S.
Narayana, Badiadka
4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
title 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
title_full 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
title_fullStr 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
title_full_unstemmed 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
title_short 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
title_sort 4-[bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201484/
https://www.ncbi.nlm.nih.gov/pubmed/22064439
http://dx.doi.org/10.1107/S160053681103580X
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