Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)

In the title co-crystal, [Fe(C(5)H(5))(C(7)H(6)ClO)][Fe(C(5)H(5))(C(7)H(7)O)], both substituted ferrocene mol­ecules show the expected sandwich structure. The crystal packing exhibits weak inter­molecular Cl⋯Cl contacts of 3.279 (4) Å, π–π inter­actions between the substituted Cp rings of two neighb...

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Detalles Bibliográficos
Autores principales: Erben, Milan, Vinklárek, Jaromír, Růžička, Aleš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201489/
https://www.ncbi.nlm.nih.gov/pubmed/22058716
http://dx.doi.org/10.1107/S1600536811038244
Descripción
Sumario:In the title co-crystal, [Fe(C(5)H(5))(C(7)H(6)ClO)][Fe(C(5)H(5))(C(7)H(7)O)], both substituted ferrocene mol­ecules show the expected sandwich structure. The crystal packing exhibits weak inter­molecular Cl⋯Cl contacts of 3.279 (4) Å, π–π inter­actions between the substituted Cp rings of two neighbouring 2-chloro-1-ferrocenyl­ethanone mol­ecules [centroid–centroid distance = 3.534 (3) Å], and weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds.

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