Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)

In the title co-crystal, [Fe(C(5)H(5))(C(7)H(6)ClO)][Fe(C(5)H(5))(C(7)H(7)O)], both substituted ferrocene mol­ecules show the expected sandwich structure. The crystal packing exhibits weak inter­molecular Cl⋯Cl contacts of 3.279 (4) Å, π–π inter­actions between the substituted Cp rings of two neighb...

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Detalles Bibliográficos
Autores principales: Erben, Milan, Vinklárek, Jaromír, Růžička, Aleš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201489/
https://www.ncbi.nlm.nih.gov/pubmed/22058716
http://dx.doi.org/10.1107/S1600536811038244
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author Erben, Milan
Vinklárek, Jaromír
Růžička, Aleš
author_facet Erben, Milan
Vinklárek, Jaromír
Růžička, Aleš
author_sort Erben, Milan
collection PubMed
description In the title co-crystal, [Fe(C(5)H(5))(C(7)H(6)ClO)][Fe(C(5)H(5))(C(7)H(7)O)], both substituted ferrocene mol­ecules show the expected sandwich structure. The crystal packing exhibits weak inter­molecular Cl⋯Cl contacts of 3.279 (4) Å, π–π inter­actions between the substituted Cp rings of two neighbouring 2-chloro-1-ferrocenyl­ethanone mol­ecules [centroid–centroid distance = 3.534 (3) Å], and weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds.
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spelling pubmed-32014892011-11-06 Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1) Erben, Milan Vinklárek, Jaromír Růžička, Aleš Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title co-crystal, [Fe(C(5)H(5))(C(7)H(6)ClO)][Fe(C(5)H(5))(C(7)H(7)O)], both substituted ferrocene mol­ecules show the expected sandwich structure. The crystal packing exhibits weak inter­molecular Cl⋯Cl contacts of 3.279 (4) Å, π–π inter­actions between the substituted Cp rings of two neighbouring 2-chloro-1-ferrocenyl­ethanone mol­ecules [centroid–centroid distance = 3.534 (3) Å], and weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201489/ /pubmed/22058716 http://dx.doi.org/10.1107/S1600536811038244 Text en © Erben et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Erben, Milan
Vinklárek, Jaromír
Růžička, Aleš
Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)
title Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)
title_full Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)
title_fullStr Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)
title_full_unstemmed Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)
title_short Acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)
title_sort acetyl­ferrocene–2-chloro-1-ferrocenyl­ethanone (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201489/
https://www.ncbi.nlm.nih.gov/pubmed/22058716
http://dx.doi.org/10.1107/S1600536811038244
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