Diaqua­dichloridobis(pyridine-κN)manganese(II)

The molecular title compound, [MnCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], lies about an inversion centre. The Mn(II) atom is in an all-trans octa­hedral environment defined by two water mol­ecules, two chloride anions and two pyridine ligands. An inter­molecular hydrogen-bonding inter­action between a water...

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Detalles Bibliográficos
Autores principales: Karthikeyan, M., Karthikeyan, S., Manimaran, Bala.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201495/
https://www.ncbi.nlm.nih.gov/pubmed/22064913
http://dx.doi.org/10.1107/S160053681103546X
Descripción
Sumario:The molecular title compound, [MnCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], lies about an inversion centre. The Mn(II) atom is in an all-trans octa­hedral environment defined by two water mol­ecules, two chloride anions and two pyridine ligands. An inter­molecular hydrogen-bonding inter­action between a water mol­ecule and a chloride anion bonded to an adjacent Mn(II) atom generates an eight-membered ring. The crystal packing exhibits two inter­molecular π–π stacking inter­actions between the aromatic rings, with centroid–centroid distances of 3.485 (12) and 3.532 (12) Å.

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