Diaqua­dichloridobis(pyridine-κN)manganese(II)

The molecular title compound, [MnCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], lies about an inversion centre. The Mn(II) atom is in an all-trans octa­hedral environment defined by two water mol­ecules, two chloride anions and two pyridine ligands. An inter­molecular hydrogen-bonding inter­action between a water...

Descripción completa

Detalles Bibliográficos
Autores principales: Karthikeyan, M., Karthikeyan, S., Manimaran, Bala.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201495/
https://www.ncbi.nlm.nih.gov/pubmed/22064913
http://dx.doi.org/10.1107/S160053681103546X
_version_ 1782214887792967680
author Karthikeyan, M.
Karthikeyan, S.
Manimaran, Bala.
author_facet Karthikeyan, M.
Karthikeyan, S.
Manimaran, Bala.
author_sort Karthikeyan, M.
collection PubMed
description The molecular title compound, [MnCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], lies about an inversion centre. The Mn(II) atom is in an all-trans octa­hedral environment defined by two water mol­ecules, two chloride anions and two pyridine ligands. An inter­molecular hydrogen-bonding inter­action between a water mol­ecule and a chloride anion bonded to an adjacent Mn(II) atom generates an eight-membered ring. The crystal packing exhibits two inter­molecular π–π stacking inter­actions between the aromatic rings, with centroid–centroid distances of 3.485 (12) and 3.532 (12) Å.
format Online
Article
Text
id pubmed-3201495
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32014952011-11-06 Diaqua­dichloridobis(pyridine-κN)manganese(II) Karthikeyan, M. Karthikeyan, S. Manimaran, Bala. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecular title compound, [MnCl(2)(C(5)H(5)N)(2)(H(2)O)(2)], lies about an inversion centre. The Mn(II) atom is in an all-trans octa­hedral environment defined by two water mol­ecules, two chloride anions and two pyridine ligands. An inter­molecular hydrogen-bonding inter­action between a water mol­ecule and a chloride anion bonded to an adjacent Mn(II) atom generates an eight-membered ring. The crystal packing exhibits two inter­molecular π–π stacking inter­actions between the aromatic rings, with centroid–centroid distances of 3.485 (12) and 3.532 (12) Å. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201495/ /pubmed/22064913 http://dx.doi.org/10.1107/S160053681103546X Text en © Karthikeyan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Karthikeyan, M.
Karthikeyan, S.
Manimaran, Bala.
Diaqua­dichloridobis(pyridine-κN)manganese(II)
title Diaqua­dichloridobis(pyridine-κN)manganese(II)
title_full Diaqua­dichloridobis(pyridine-κN)manganese(II)
title_fullStr Diaqua­dichloridobis(pyridine-κN)manganese(II)
title_full_unstemmed Diaqua­dichloridobis(pyridine-κN)manganese(II)
title_short Diaqua­dichloridobis(pyridine-κN)manganese(II)
title_sort diaqua­dichloridobis(pyridine-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201495/
https://www.ncbi.nlm.nih.gov/pubmed/22064913
http://dx.doi.org/10.1107/S160053681103546X
work_keys_str_mv AT karthikeyanm diaquadichloridobispyridineknmanganeseii
AT karthikeyans diaquadichloridobispyridineknmanganeseii
AT manimaranbala diaquadichloridobispyridineknmanganeseii

Ejemplares similares