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rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate
The racemic title compound, [FePdCl(2)(C(5)H(5))(C(36)H(29)P(2))]·2(CH(3))(2)SO, features a Pd-chelating 1,3-diphosphine, which is substituted at a P-bearing asymmetric C atom by a ferrocenyl group. The Pd(II) atom is in a distorted quadratic coordination by two P and two Cl atoms with bond lengths...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201499/ https://www.ncbi.nlm.nih.gov/pubmed/22064964 http://dx.doi.org/10.1107/S160053681103618X |
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author | Schuecker, Raffael Weissensteiner, Walter Mereiter, Kurt |
author_facet | Schuecker, Raffael Weissensteiner, Walter Mereiter, Kurt |
author_sort | Schuecker, Raffael |
collection | PubMed |
description | The racemic title compound, [FePdCl(2)(C(5)H(5))(C(36)H(29)P(2))]·2(CH(3))(2)SO, features a Pd-chelating 1,3-diphosphine, which is substituted at a P-bearing asymmetric C atom by a ferrocenyl group. The Pd(II) atom is in a distorted quadratic coordination by two P and two Cl atoms with bond lengths of 2.2414 (3) and 2.2438 (3) Å for Pd—P, and 2.3452 (3) and 2.3565 (3) Å for Pd—Cl. The conformation of the Pd complex is controlled by an intramolecular slipped π–π stacking interaction between a phenyl and a cyclopentadienyl ring with corresponding C⋯C distances starting at 3.300 (2) Å and the distance between ring centroids being 3.674 (2) Å. The crystal structure is stabilized by C—H⋯Cl and C—H⋯O hydrogen bonds. The (CH(3))(2)SO solvent molecules are arranged in layers parallel to (101) and are linked in pairs by C—H⋯O interactions. One (CH(3))(2)SO molecule is orientationally disordered [occupancy ratio 0.8766 (17):0.1234 (17)] with sulfur in two positions at both sides of its C(2)O triangle. |
format | Online Article Text |
id | pubmed-3201499 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32014992011-11-06 rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate Schuecker, Raffael Weissensteiner, Walter Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The racemic title compound, [FePdCl(2)(C(5)H(5))(C(36)H(29)P(2))]·2(CH(3))(2)SO, features a Pd-chelating 1,3-diphosphine, which is substituted at a P-bearing asymmetric C atom by a ferrocenyl group. The Pd(II) atom is in a distorted quadratic coordination by two P and two Cl atoms with bond lengths of 2.2414 (3) and 2.2438 (3) Å for Pd—P, and 2.3452 (3) and 2.3565 (3) Å for Pd—Cl. The conformation of the Pd complex is controlled by an intramolecular slipped π–π stacking interaction between a phenyl and a cyclopentadienyl ring with corresponding C⋯C distances starting at 3.300 (2) Å and the distance between ring centroids being 3.674 (2) Å. The crystal structure is stabilized by C—H⋯Cl and C—H⋯O hydrogen bonds. The (CH(3))(2)SO solvent molecules are arranged in layers parallel to (101) and are linked in pairs by C—H⋯O interactions. One (CH(3))(2)SO molecule is orientationally disordered [occupancy ratio 0.8766 (17):0.1234 (17)] with sulfur in two positions at both sides of its C(2)O triangle. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201499/ /pubmed/22064964 http://dx.doi.org/10.1107/S160053681103618X Text en © Schuecker et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Schuecker, Raffael Weissensteiner, Walter Mereiter, Kurt rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate |
title |
rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2)
P,P′)palladium(II) dimethyl sulfoxide disolvate |
title_full |
rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2)
P,P′)palladium(II) dimethyl sulfoxide disolvate |
title_fullStr |
rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2)
P,P′)palladium(II) dimethyl sulfoxide disolvate |
title_full_unstemmed |
rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2)
P,P′)palladium(II) dimethyl sulfoxide disolvate |
title_short |
rac-Dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2)
P,P′)palladium(II) dimethyl sulfoxide disolvate |
title_sort | rac-dichlorido(1-{(diphenylphosphanyl)[2-(diphenylphosphanyl)phenyl]methyl}ferrocene-κ(2)
p,p′)palladium(ii) dimethyl sulfoxide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201499/ https://www.ncbi.nlm.nih.gov/pubmed/22064964 http://dx.doi.org/10.1107/S160053681103618X |
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