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rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate

The racemic title compound, [FePdCl(2)(C(5)H(5))(C(36)H(29)P(2))]·2(CH(3))(2)SO, features a Pd-chelating 1,3-diphosphine, which is substituted at a P-bearing asymmetric C atom by a ferrocenyl group. The Pd(II) atom is in a distorted quadratic coordination by two P and two Cl atoms with bond lengths...

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Detalles Bibliográficos
Autores principales: Schuecker, Raffael, Weissensteiner, Walter, Mereiter, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201499/
https://www.ncbi.nlm.nih.gov/pubmed/22064964
http://dx.doi.org/10.1107/S160053681103618X
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author Schuecker, Raffael
Weissensteiner, Walter
Mereiter, Kurt
author_facet Schuecker, Raffael
Weissensteiner, Walter
Mereiter, Kurt
author_sort Schuecker, Raffael
collection PubMed
description The racemic title compound, [FePdCl(2)(C(5)H(5))(C(36)H(29)P(2))]·2(CH(3))(2)SO, features a Pd-chelating 1,3-diphosphine, which is substituted at a P-bearing asymmetric C atom by a ferrocenyl group. The Pd(II) atom is in a distorted quadratic coordination by two P and two Cl atoms with bond lengths of 2.2414 (3) and 2.2438 (3) Å for Pd—P, and 2.3452 (3) and 2.3565 (3) Å for Pd—Cl. The conformation of the Pd complex is controlled by an intra­molecular slipped π–π stacking inter­action between a phenyl and a cyclo­penta­dienyl ring with corresponding C⋯C distances starting at 3.300 (2) Å and the distance between ring centroids being 3.674 (2) Å. The crystal structure is stabilized by C—H⋯Cl and C—H⋯O hydrogen bonds. The (CH(3))(2)SO solvent mol­ecules are arranged in layers parallel to (101) and are linked in pairs by C—H⋯O inter­actions. One (CH(3))(2)SO mol­ecule is orientationally disordered [occupancy ratio 0.8766 (17):0.1234 (17)] with sulfur in two positions at both sides of its C(2)O triangle.
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spelling pubmed-32014992011-11-06 rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate Schuecker, Raffael Weissensteiner, Walter Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The racemic title compound, [FePdCl(2)(C(5)H(5))(C(36)H(29)P(2))]·2(CH(3))(2)SO, features a Pd-chelating 1,3-diphosphine, which is substituted at a P-bearing asymmetric C atom by a ferrocenyl group. The Pd(II) atom is in a distorted quadratic coordination by two P and two Cl atoms with bond lengths of 2.2414 (3) and 2.2438 (3) Å for Pd—P, and 2.3452 (3) and 2.3565 (3) Å for Pd—Cl. The conformation of the Pd complex is controlled by an intra­molecular slipped π–π stacking inter­action between a phenyl and a cyclo­penta­dienyl ring with corresponding C⋯C distances starting at 3.300 (2) Å and the distance between ring centroids being 3.674 (2) Å. The crystal structure is stabilized by C—H⋯Cl and C—H⋯O hydrogen bonds. The (CH(3))(2)SO solvent mol­ecules are arranged in layers parallel to (101) and are linked in pairs by C—H⋯O inter­actions. One (CH(3))(2)SO mol­ecule is orientationally disordered [occupancy ratio 0.8766 (17):0.1234 (17)] with sulfur in two positions at both sides of its C(2)O triangle. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201499/ /pubmed/22064964 http://dx.doi.org/10.1107/S160053681103618X Text en © Schuecker et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schuecker, Raffael
Weissensteiner, Walter
Mereiter, Kurt
rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate
title rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate
title_full rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate
title_fullStr rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate
title_full_unstemmed rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate
title_short rac-Dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) P,P′)palladium(II) dimethyl sulfoxide disolvate
title_sort rac-dichlorido(1-{(diphenyl­phosphan­yl)[2-(diphenyl­phosphan­yl)phen­yl]meth­yl}ferrocene-κ(2) p,p′)palladium(ii) dimethyl sulfoxide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201499/
https://www.ncbi.nlm.nih.gov/pubmed/22064964
http://dx.doi.org/10.1107/S160053681103618X
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AT mereiterkurt racdichlorido1diphenylphosphanyl2diphenylphosphanylphenylmethylferrocenek2pppalladiumiidimethylsulfoxidedisolvate