Aqua­chloridobis(2-eth­oxy-6-formyl­phenolato-κ(2) O (1),O (6))chromium(III) acetonitrile hemisolvate

In the mononuclear complex mol­ecule of the title compound, [Cr(C(9)H(9)O(3))(2)Cl(H(2)O)]·0.5CH(3)CN, the Cr(III) atom displays an elongated octa­hedral coordination geometry. The dihedral angle between the benzene rings is 12.27 (11)°. Adjacent complex mol­ecules are linked into dimers by O—H⋯O hy...

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Detalles Bibliográficos
Autores principales: Ghelenji, Safoora, Kargar, Hadi, Sharafi, Zahra, Kia, Reza
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201503/
https://www.ncbi.nlm.nih.gov/pubmed/22065117
http://dx.doi.org/10.1107/S1600536811037275
Descripción
Sumario:In the mononuclear complex mol­ecule of the title compound, [Cr(C(9)H(9)O(3))(2)Cl(H(2)O)]·0.5CH(3)CN, the Cr(III) atom displays an elongated octa­hedral coordination geometry. The dihedral angle between the benzene rings is 12.27 (11)°. Adjacent complex mol­ecules are linked into dimers by O—H⋯O hydrogen bonds, generating rings of R (1) (2)(6) and R (1) (2)(5) graph-set motifs, and by aromatic π–π stacking inter­actions, with a centroid–centroid distance of 3.812 (2) Å. The crystal packing is further stabilized by inter­molecular C—H⋯N hydrogen bonds. The C and N atoms of the acetonitrile solvent mol­ecule are located on a crystallographic twofold axis.

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