Cargando…
Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2) O (1),O (6))chromium(III) acetonitrile hemisolvate
In the mononuclear complex molecule of the title compound, [Cr(C(9)H(9)O(3))(2)Cl(H(2)O)]·0.5CH(3)CN, the Cr(III) atom displays an elongated octahedral coordination geometry. The dihedral angle between the benzene rings is 12.27 (11)°. Adjacent complex molecules are linked into dimers by O—H⋯O hy...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201503/ https://www.ncbi.nlm.nih.gov/pubmed/22065117 http://dx.doi.org/10.1107/S1600536811037275 |
| _version_ | 1782214889670967296 |
|---|---|
| author | Ghelenji, Safoora Kargar, Hadi Sharafi, Zahra Kia, Reza |
| author_facet | Ghelenji, Safoora Kargar, Hadi Sharafi, Zahra Kia, Reza |
| author_sort | Ghelenji, Safoora |
| collection | PubMed |
| description | In the mononuclear complex molecule of the title compound, [Cr(C(9)H(9)O(3))(2)Cl(H(2)O)]·0.5CH(3)CN, the Cr(III) atom displays an elongated octahedral coordination geometry. The dihedral angle between the benzene rings is 12.27 (11)°. Adjacent complex molecules are linked into dimers by O—H⋯O hydrogen bonds, generating rings of R (1) (2)(6) and R (1) (2)(5) graph-set motifs, and by aromatic π–π stacking interactions, with a centroid–centroid distance of 3.812 (2) Å. The crystal packing is further stabilized by intermolecular C—H⋯N hydrogen bonds. The C and N atoms of the acetonitrile solvent molecule are located on a crystallographic twofold axis. |
| format | Online Article Text |
| id | pubmed-3201503 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32015032011-11-06 Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2) O (1),O (6))chromium(III) acetonitrile hemisolvate Ghelenji, Safoora Kargar, Hadi Sharafi, Zahra Kia, Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear complex molecule of the title compound, [Cr(C(9)H(9)O(3))(2)Cl(H(2)O)]·0.5CH(3)CN, the Cr(III) atom displays an elongated octahedral coordination geometry. The dihedral angle between the benzene rings is 12.27 (11)°. Adjacent complex molecules are linked into dimers by O—H⋯O hydrogen bonds, generating rings of R (1) (2)(6) and R (1) (2)(5) graph-set motifs, and by aromatic π–π stacking interactions, with a centroid–centroid distance of 3.812 (2) Å. The crystal packing is further stabilized by intermolecular C—H⋯N hydrogen bonds. The C and N atoms of the acetonitrile solvent molecule are located on a crystallographic twofold axis. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201503/ /pubmed/22065117 http://dx.doi.org/10.1107/S1600536811037275 Text en © Ghelenji et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ghelenji, Safoora Kargar, Hadi Sharafi, Zahra Kia, Reza Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2) O (1),O (6))chromium(III) acetonitrile hemisolvate |
| title | Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))chromium(III) acetonitrile hemisolvate |
| title_full | Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))chromium(III) acetonitrile hemisolvate |
| title_fullStr | Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))chromium(III) acetonitrile hemisolvate |
| title_full_unstemmed | Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))chromium(III) acetonitrile hemisolvate |
| title_short | Aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
O
(1),O
(6))chromium(III) acetonitrile hemisolvate |
| title_sort | aquachloridobis(2-ethoxy-6-formylphenolato-κ(2)
o
(1),o
(6))chromium(iii) acetonitrile hemisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201503/ https://www.ncbi.nlm.nih.gov/pubmed/22065117 http://dx.doi.org/10.1107/S1600536811037275 |
| work_keys_str_mv | AT ghelenjisafoora aquachloridobis2ethoxy6formylphenolatok2o1o6chromiumiiiacetonitrilehemisolvate AT kargarhadi aquachloridobis2ethoxy6formylphenolatok2o1o6chromiumiiiacetonitrilehemisolvate AT sharafizahra aquachloridobis2ethoxy6formylphenolatok2o1o6chromiumiiiacetonitrilehemisolvate AT kiareza aquachloridobis2ethoxy6formylphenolatok2o1o6chromiumiiiacetonitrilehemisolvate |