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catena-Poly[[bis(3-methylbenzoato-κ(2) O,O′)lead(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
In the title complex, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))](n), the Pb(II) atom is located on a twofold rotation axis and is six-coordinated by four carboxylate O atoms from two 3-methylbenzoate ligands and two N atoms from two 4,4′-bipyridine (4,4′-bpy) ligands, displaying a hemi-directed coordina...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201505/ https://www.ncbi.nlm.nih.gov/pubmed/22065196 http://dx.doi.org/10.1107/S1600536811035021 |
Sumario: | In the title complex, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))](n), the Pb(II) atom is located on a twofold rotation axis and is six-coordinated by four carboxylate O atoms from two 3-methylbenzoate ligands and two N atoms from two 4,4′-bipyridine (4,4′-bpy) ligands, displaying a hemi-directed coordination. The 4,4′-bpy ligand has an inversion center at the mid-point of the central C—C bond. The Pb(II) atoms are linked by bidentate bridging 4,4′-bpy into a chain along [101]. These chains are further connected into layers via C—H⋯O hydrogen bonds. |
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