catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]

In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra­hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu–Cu separation of 3.0120...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Loh, Wan-Sin, Patra, Goutam K., Mukherjee, Anindita, Pal, Pankaj K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201507/
https://www.ncbi.nlm.nih.gov/pubmed/22058699
http://dx.doi.org/10.1107/S1600536811036555
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author Fun, Hoong-Kun
Loh, Wan-Sin
Patra, Goutam K.
Mukherjee, Anindita
Pal, Pankaj K.
author_facet Fun, Hoong-Kun
Loh, Wan-Sin
Patra, Goutam K.
Mukherjee, Anindita
Pal, Pankaj K.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra­hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu–Cu separation of 3.0120 (5) Å. The complete N,N′-(1-pyridin-4-yl-ethethyl­idene)-hydrazine mol­ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.
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spelling pubmed-32015072011-11-06 catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}] Fun, Hoong-Kun Loh, Wan-Sin Patra, Goutam K. Mukherjee, Anindita Pal, Pankaj K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra­hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu–Cu separation of 3.0120 (5) Å. The complete N,N′-(1-pyridin-4-yl-ethethyl­idene)-hydrazine mol­ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201507/ /pubmed/22058699 http://dx.doi.org/10.1107/S1600536811036555 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fun, Hoong-Kun
Loh, Wan-Sin
Patra, Goutam K.
Mukherjee, Anindita
Pal, Pankaj K.
catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]
title catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]
title_full catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]
title_fullStr catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]
title_full_unstemmed catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]
title_short catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]
title_sort catena-poly[[(triphenyl­phosphane)copper(i)]-di-μ-iodido-[(triphenyl­phosphane)copper(i)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201507/
https://www.ncbi.nlm.nih.gov/pubmed/22058699
http://dx.doi.org/10.1107/S1600536811036555
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