catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)]

The title complex, [Tb(2)(C(6)H(4)NO(2))(6)(H(2)O)(4)](n), was isolated under hydro­thermal conditions using the ligand pyridine-4-carb­oxy­lic acid (HL) and Tb(2)O(3). The deprotonated L (2−) ligands adopt bridging coordination modes. The central Tb(III) atom is bridged by L (2−) ligands, forming a...

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Detalles Bibliográficos
Autores principales: Zhang, Xiangfei, Zhai, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201511/
https://www.ncbi.nlm.nih.gov/pubmed/22065634
http://dx.doi.org/10.1107/S1600536811038487
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author Zhang, Xiangfei
Zhai, Bin
author_facet Zhang, Xiangfei
Zhai, Bin
author_sort Zhang, Xiangfei
collection PubMed
description The title complex, [Tb(2)(C(6)H(4)NO(2))(6)(H(2)O)(4)](n), was isolated under hydro­thermal conditions using the ligand pyridine-4-carb­oxy­lic acid (HL) and Tb(2)O(3). The deprotonated L (2−) ligands adopt bridging coordination modes. The central Tb(III) atom is bridged by L (2−) ligands, forming a polymeric chain parallel to the a axis. Supra­molecular O—H⋯N inter­actions link the chains, building up a layer parallel to (010). O—H⋯O hydrogen bonds also occur. Two of the pyridine rings are disordered by rotation around the central C—N direction with occupancy ratios of 0.53 (1):0.47 (1).
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spelling pubmed-32015112011-11-06 catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)] Zhang, Xiangfei Zhai, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Tb(2)(C(6)H(4)NO(2))(6)(H(2)O)(4)](n), was isolated under hydro­thermal conditions using the ligand pyridine-4-carb­oxy­lic acid (HL) and Tb(2)O(3). The deprotonated L (2−) ligands adopt bridging coordination modes. The central Tb(III) atom is bridged by L (2−) ligands, forming a polymeric chain parallel to the a axis. Supra­molecular O—H⋯N inter­actions link the chains, building up a layer parallel to (010). O—H⋯O hydrogen bonds also occur. Two of the pyridine rings are disordered by rotation around the central C—N direction with occupancy ratios of 0.53 (1):0.47 (1). International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201511/ /pubmed/22065634 http://dx.doi.org/10.1107/S1600536811038487 Text en © Zhang and Zhai 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiangfei
Zhai, Bin
catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)]
title catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)]
title_full catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)]
title_fullStr catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)]
title_full_unstemmed catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)]
title_short catena-Poly[[diaquaterbium(III)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)-[diaquaterbium(III)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) O:O′)]
title_sort catena-poly[[diaquaterbium(iii)]-tetrakis(μ(2)-pyridine-4-carboxylato-κ(2) o:o′)-[diaquaterbium(iii)]-bis(μ(2)-pyridine-4-carboxylato-κ(2) o:o′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201511/
https://www.ncbi.nlm.nih.gov/pubmed/22065634
http://dx.doi.org/10.1107/S1600536811038487
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