Cargando…

Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate

The asymmetric unit of the title compound, [MnI(C(24)H(16)N(6))(H(2)O)(2)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water mol­ecule. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octa­hedral environment defined by three N atoms of the...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201512/
https://www.ncbi.nlm.nih.gov/pubmed/22058685
http://dx.doi.org/10.1107/S1600536811035434
_version_ 1782214891713593344
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The asymmetric unit of the title compound, [MnI(C(24)H(16)N(6))(H(2)O)(2)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water mol­ecule. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octa­hedral environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine (tppz) ligand, one I(−) anion and two O atoms of two water ligands. The dihedral angles between the pyridyl rings [maximum deviation = 0.034 (6) Å] and their carrier pyrazine ring [maximum deviation = 0.020 (6) Å] are 26.5 (2) and 27.0 (2)° for the coordinated pyridyl rings, and 51.3 (3) and 43.2 (2)° for the uncoordinated pyridyl rings. Inter­molecular O—H⋯O, O—H⋯N and O—H⋯I hydrogen bonds stabilize the crystal structure.
format Online
Article
Text
id pubmed-3201512
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32015122011-11-06 Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [MnI(C(24)H(16)N(6))(H(2)O)(2)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water mol­ecule. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octa­hedral environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridyl­pyrazine (tppz) ligand, one I(−) anion and two O atoms of two water ligands. The dihedral angles between the pyridyl rings [maximum deviation = 0.034 (6) Å] and their carrier pyrazine ring [maximum deviation = 0.020 (6) Å] are 26.5 (2) and 27.0 (2)° for the coordinated pyridyl rings, and 51.3 (3) and 43.2 (2)° for the uncoordinated pyridyl rings. Inter­molecular O—H⋯O, O—H⋯N and O—H⋯I hydrogen bonds stabilize the crystal structure. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201512/ /pubmed/22058685 http://dx.doi.org/10.1107/S1600536811035434 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate
title Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate
title_full Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate
title_fullStr Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate
title_full_unstemmed Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate
title_short Diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate
title_sort diaqua­iodido(2,3,5,6-tetra-2-pyridyl­pyrazine-κ(3) n (2),n (1),n (6))manganese(ii) iodide monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201512/
https://www.ncbi.nlm.nih.gov/pubmed/22058685
http://dx.doi.org/10.1107/S1600536811035434
work_keys_str_mv AT hakwang diaquaiodido2356tetra2pyridylpyrazinek3n2n1n6manganeseiiiodidemonohydrate