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Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate
The asymmetric unit of the title compound, [MnI(C(24)H(16)N(6))(H(2)O)(2)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water molecule. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octahedral environment defined by three N atoms of the...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201512/ https://www.ncbi.nlm.nih.gov/pubmed/22058685 http://dx.doi.org/10.1107/S1600536811035434 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The asymmetric unit of the title compound, [MnI(C(24)H(16)N(6))(H(2)O)(2)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water molecule. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octahedral environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine (tppz) ligand, one I(−) anion and two O atoms of two water ligands. The dihedral angles between the pyridyl rings [maximum deviation = 0.034 (6) Å] and their carrier pyrazine ring [maximum deviation = 0.020 (6) Å] are 26.5 (2) and 27.0 (2)° for the coordinated pyridyl rings, and 51.3 (3) and 43.2 (2)° for the uncoordinated pyridyl rings. Intermolecular O—H⋯O, O—H⋯N and O—H⋯I hydrogen bonds stabilize the crystal structure. |
format | Online Article Text |
id | pubmed-3201512 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32015122011-11-06 Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [MnI(C(24)H(16)N(6))(H(2)O)(2)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water molecule. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octahedral environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine (tppz) ligand, one I(−) anion and two O atoms of two water ligands. The dihedral angles between the pyridyl rings [maximum deviation = 0.034 (6) Å] and their carrier pyrazine ring [maximum deviation = 0.020 (6) Å] are 26.5 (2) and 27.0 (2)° for the coordinated pyridyl rings, and 51.3 (3) and 43.2 (2)° for the uncoordinated pyridyl rings. Intermolecular O—H⋯O, O—H⋯N and O—H⋯I hydrogen bonds stabilize the crystal structure. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201512/ /pubmed/22058685 http://dx.doi.org/10.1107/S1600536811035434 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3) N (2),N (1),N (6))manganese(II) iodide monohydrate |
title | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) iodide monohydrate |
title_full | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) iodide monohydrate |
title_fullStr | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) iodide monohydrate |
title_full_unstemmed | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) iodide monohydrate |
title_short | Diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) iodide monohydrate |
title_sort | diaquaiodido(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
n
(2),n
(1),n
(6))manganese(ii) iodide monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201512/ https://www.ncbi.nlm.nih.gov/pubmed/22058685 http://dx.doi.org/10.1107/S1600536811035434 |
work_keys_str_mv | AT hakwang diaquaiodido2356tetra2pyridylpyrazinek3n2n1n6manganeseiiiodidemonohydrate |