Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV)

The title dinuclear titanocene, [Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O], contains one Ti atom tetra­hedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclo­penta­dienyl ligand, and another Ti atom tetra­hedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethy...

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Detalles Bibliográficos
Autores principales: Luo, Xuyang, Wu, Qiaolin, Mu, Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201525/
https://www.ncbi.nlm.nih.gov/pubmed/22064795
http://dx.doi.org/10.1107/S1600536811035306
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author Luo, Xuyang
Wu, Qiaolin
Mu, Ying
author_facet Luo, Xuyang
Wu, Qiaolin
Mu, Ying
author_sort Luo, Xuyang
collection PubMed
description The title dinuclear titanocene, [Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O], contains one Ti atom tetra­hedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclo­penta­dienyl ligand, and another Ti atom tetra­hedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethyl­phenolate ligand and the substituted cyclo­penta­dienyl ligand. The bridging O atom lies on a twofold rotation axis.
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spelling pubmed-32015252011-11-06 Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV) Luo, Xuyang Wu, Qiaolin Mu, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear titanocene, [Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O], contains one Ti atom tetra­hedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclo­penta­dienyl ligand, and another Ti atom tetra­hedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethyl­phenolate ligand and the substituted cyclo­penta­dienyl ligand. The bridging O atom lies on a twofold rotation axis. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201525/ /pubmed/22064795 http://dx.doi.org/10.1107/S1600536811035306 Text en © Luo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Xuyang
Wu, Qiaolin
Mu, Ying
Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV)
title Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV)
title_full Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV)
title_fullStr Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV)
title_full_unstemmed Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV)
title_short Trichlorido-1κ(2) Cl,2κCl-(2,6-dimethyl­phenolato-2κO)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(IV)
title_sort trichlorido-1κ(2) cl,2κcl-(2,6-dimethyl­phenolato-2κo)-μ-oxido-bis{1,2(η(5))-2,3,4,5-tetra­methyl-1-[4-(trimethyl­silyl)phen­yl]cyclo­penta­dien­yl}dititanium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201525/
https://www.ncbi.nlm.nih.gov/pubmed/22064795
http://dx.doi.org/10.1107/S1600536811035306
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AT wuqiaolin trichlorido1k2cl2kcl26dimethylphenolato2komoxidobis12ē52345tetramethyl14trimethylsilylphenylcyclopentadienyldititaniumiv
AT muying trichlorido1k2cl2kcl26dimethylphenolato2komoxidobis12ē52345tetramethyl14trimethylsilylphenylcyclopentadienyldititaniumiv

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